Hydrogen sulphide detection using near-infrared diode laser and compact dense-pattern multipass cell

doi:10.1088/1674-1056/28/6/063301

Abstract

Sub-ppmv level detection of hydrogen sulphide (H₂S) using a 1.578-μm distributed feedback tunable diode laser combining with wavelength modulation spectroscopy and second harmonic detection scheme is reported. A home-developed novel compact dense-pattern multipass gas cell with an effective optical path length of 29.37 m is used to improve sensitivity and reduce sample volume. Detection parameters are optimized, including modulation frequency and amplitude. The analysis of Allan variance shows that a minimum detectable concentration 60 ppbv is obtained with a lock-in time constant of 10 ms, and a detection limit of 13 ppbv can be achieved by average in 300 s. The demonstrated H₂S sensor has a strong penitential application in natural gas process for regulating and controlling H₂S concentration.

Keywords: hydrogen sulphide wavelength modulation spectroscopy second harmonic detection detection limit

Received: 11 March 2019
Revised: 11 April 2019
Accepted manuscript online:

PACS:	33.20.Ea	(Infrared spectra)
	42.55.-f	(Lasers)
	42.62.-b	(Laser applications)
	42.62.Fi	(Laser spectroscopy)

Fund:

Project supported by the National Key Research and Development Program of China (Grant Nos. 2016YFC0303900 and 2017YFC0209700).

Corresponding Authors: Kun Liu
E-mail: liukun@aiofm.ac.cn

Cite this article:

Xing Tian(田兴), Yuan Cao(曹渊), Jia-Jin Chen(陈家金), Kun Liu(刘锟), Gui-Shi Wang(王贵师), Xiao-Ming Gao(高晓明) Hydrogen sulphide detection using near-infrared diode laser and compact dense-pattern multipass cell 2019 Chin. Phys. B 28 063301

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Hydrogen sulphide detection using near-infrared diode laser and compact dense-pattern multipass cell

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