Please wait a minute...
Chin. Phys. B, 2019, Vol. 28(1): 016103    DOI: 10.1088/1674-1056/28/1/016103
CONDENSED MATTER: STRUCTURAL, MECHANICAL, AND THERMAL PROPERTIES Prev   Next  

Effects of deuteration on the structure of NH4H2PO4 crystals characterized by neutron diffraction

Baoan Liu(刘宝安)1, Lili Zhu(朱丽丽)2, Fafu Liu(刘发付)3,4, Xun Sun(孙洵)3, Xiping Chen(陈喜平)4, Lei Xie(谢雷)4, Yuanhua Xia(夏元华)4, Guangai Sun(孙光爱)4, Xin Ju(巨新)1,4
1 Department of Physics, University of Science and Technology Beijing, Beijing 100083, China;
2 School of Materials Science and Engineering, Shandong Jiaotong University, Jinan 250357, China;
3 State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, China;
4 Neutron Physics Laboratory, China Academy of Engineering Physics, Mianyang 621900, China
Abstract  

A series of deuterated ammonium dihydrogen phosphate (DADP) crystals were grown and their structures were investigated by using powder neutron diffraction method. In the entire composition range, the deuterated level in the crystals is lower compared with the aqueous growth solution. The deuterium segregation coefficient in the crystals decreases with increasing deuterium content of the solution. The deuterium content in the NH4+ group is higher than that in H2PO4- group. In addition, the variations of lattice parameters are shown here.

Keywords:  DADP crystal      neutron diffraction      deuteration level  
Received:  18 October 2018      Revised:  11 November 2018      Accepted manuscript online: 
PACS:  61.05.F- (Neutron diffraction and scattering)  
  61.50.-f (Structure of bulk crystals)  
  81.10.Dn (Growth from solutions)  
Fund: 

Project supported by the National Natural Science Foundation of China (Grant No. 51402173), Shandong Provincial Natural Science Joint Foundation with Universities and Scientific Research Institution, China (Grant No. ZR2017LEM006), the Neutron Physics Laboratory, China Academy of Engineering Physics (Grant No. 2014BB07), and the Fundamental Research Funds for Central Universities, China (Grant No. FRF-TP-15-099A1).

Corresponding Authors:  Lili Zhu     E-mail:  zhullcrys@163.com

Cite this article: 

Baoan Liu(刘宝安), Lili Zhu(朱丽丽), Fafu Liu(刘发付), Xun Sun(孙洵), Xiping Chen(陈喜平), Lei Xie(谢雷), Yuanhua Xia(夏元华), Guangai Sun(孙光爱), Xin Ju(巨新) Effects of deuteration on the structure of NH4H2PO4 crystals characterized by neutron diffraction 2019 Chin. Phys. B 28 016103

[1] Boyd G D, Ashkin A, Dziedzic J M and Kleinman D A 1965 Phys. Rev. 137 A1305
[2] Dmitriev V G, Gurzadyan G G and Nikogosyan D N 1999 Handbook of Nonlinear Optical Crystals, 3rd edn. (Berlin: Springer-Verlag Berlin Heidelberg) p. 90
[3] Dhanaraj G, Byrappa K, Prasad V and Dudley M 2010 Handbook of Crystal Growth (Part C) (Berlin: Springer-Verlag Berlin Heidelberg) p. 759
[4] Ji S H, Li F Q, Wang F, Xu X G, Wang Z P and Sun X 2014 Opt. Mater. Express 4 997
[5] Liu B A, Hu G H, Zhao Y A, Xu M X, Ji S H, Zhu L L, Zhang L S, Sun X, Wang Z P and Xu X G 2013 Opt. Laser Technol. 45 469
[6] Loiacono G M, Balascio J F and Osborne W 1974 Appl. Phys. Lett. 24 455
[7] Miyoshi T, Mashiyama H, Asahi T, Kimura H and Noda Y 2011 J. Phys. Soc. Jpn. 80 044709
[8] Frazer B C and Pepinsky R 1953 Acta Cryst. 6 273
[9] Fukami T, Akahoshi S, Hukuda K and Yagi T 1987 J. Phys. Soc. Jpn. 56 4388
[10] Fukami T, Akahoshi S, Hukuda K and Yagi T 1987 J. Phys. Soc. Jpn. 56 2223
[11] Endo S, Chino T, Tsuboi S and Koto K 1989 Nature 340 452
[12] Tenzer L, Frazer B C and Pepinsky R 1958 Acta Cryst. 11 505
[13] Tun Z, Nelmes R J, Kuhs W F and Stansfield R F D 1988 J. Phys. C-Solid State Phys. 21 245
[14] Boukhris A, Souhassou M, Lecomte C, Wyncke B and Thalal A 1998 J. Phys. -Condens. Mat. 10 1621
[15] Momtaz R S and Rashkovich L N 1976 Phys. Stat. Sol. (a) 38 401
[16] Yakshin M A, Kim D W, Kim Y S, Broslavets Y Y, Sidoryuk O E and Goldstein S 1997 Laser Phys. 7 941
[17] Huser T, Hollars C W, Siekhaus W J, De Yoreo J J, Suratwala T I and Land T A 2004 Appl. Spectrosc. 58 349
[18] Ji S H, Wang F, Xu M M, Zhu L L, Xu X G, Wang Z P and Sun X 2013 Opt. Lett. 38 1679
[19] Feng L H, Hu Q W, Lei L, Fang L M, Qi L, Zhang L L, Pu M F, Kou Z L, Peng F, Chen X P, Xia Y H, Kojima Y, Ohfuji H, He D W, Chen B and Irifune T 2018 Chin. Phys. B 27 026201
[20] Rietveld H M 1967 Acta Cryst. 22 151
[21] Rietveld H M 1969 J. Appl. Cryst. 2 65
[22] McCusker L B, Von Dreele R B, Cox D E, Louër D and Scardi P 1999 J. Appl. Cryst. 32 36
[23] Sun C T and Xue D F 2014 J. Mol. Struct. 1059 338
[1] The design of 2/8-type high-pressure cell applied to in situ neutron diffraction
Chun-Jiang Xiang(向春江), Qi-Wei Hu(胡启威), Qiang Wang(王强), Lei Xie(谢雷), Xi-Ping Chen(陈喜平), Lei-Ming Fang(房雷鸣), Duan-Wei He(贺端威). Chin. Phys. B, 2019, 28(7): 070701.
[2] A single-crystal neutron diffraction study on magnetic structure of CsCo2Se2
Juanjuan Liu(刘娟娟), Jieming Sheng(盛洁明), Wei Luo(罗伟), Jinchen Wang(汪晋辰), Wei Bao(鲍威), Jinhu Yang(杨金虎), Minghu Fang(方明虎), S A Danilkin. Chin. Phys. B, 2018, 27(11): 117401.
[3] Mn-based permanent magnets
Jinbo Yang(杨金波), Wenyun Yang(杨文云), Zhuyin Shao(邵珠印), Dong Liang(梁栋), Hui Zhao(赵辉), Yuanhua Xia(夏元华), Yunbo Yang(杨云波). Chin. Phys. B, 2018, 27(11): 117503.
[4] The magnetic properties and magnetocaloric effects in binary R-T (R=Pr, Gd, Tb, Dy, Ho, Er, Tm; T=Ga, Ni, Co, Cu) intermetallic compounds
Xin-Qi Zheng(郑新奇), Bao-Gen Shen(沈保根). Chin. Phys. B, 2017, 26(2): 027501.
[5] Evolution of structure and physical properties in Al-substituted Ba-hexaferrites
Alex Trukhanov, Larisa Panina, Sergei Trukhanov, Vitalii Turchenko, Mohamed Salem. Chin. Phys. B, 2016, 25(1): 016102.
[6] A pressure calibration method for a portable wide-access “panoramic” cell
Fang Lei-Ming (房雷鸣), Wang Yun (王云), Chen Xi-Ping (陈喜平), Sun Guang-Ai (孙光爱), Chen Bo (陈波), Peng Shu-Ming (彭述明). Chin. Phys. B, 2014, 23(11): 110701.
[7] The interplay between the lattice and magnetism in La(Fe11.4Al1.6)C0.02 studied by powder neutron diffraction
Wang Zhi-Cui(王志翠), He Lun-Hua(何伦华), Wang Hai(王海), Liu Rong-Deng(刘荣灯), and Wang Fang-Wei(王芳卫) . Chin. Phys. B, 2012, 21(4): 046101.
[8] Determination of the sites of Fe atoms in Fe-substituted Mn12
Cao Hui-Bo(曹慧波), Chen Dong-Liang(陈栋梁), He Lun-Hua(何伦华), Zhang Jun-Rong(张俊荣), Wang Fang-Wei(王芳卫), Wu Zi-Yu(吴自玉), and Yan Qi-Wei(严启伟). Chin. Phys. B, 2007, 16(3): 784-787.
[9] Crystallographic and magnetic structures of Pr6Fe13Ge studied by powder neutron diffraction
Wang Fang-Wei (王芳卫), Zhang Pan-Lin (张泮霖), Shen Bao-Gen (沈保根), Yan Qi-Wei (严启伟). Chin. Phys. B, 2004, 13(6): 918-923.
[10] Magnetic properties of Nd0.5Pb0.5-xSrxMnO3 materials
Lu Yi (鲁毅), Li Qing-An (李庆安), Di Nai-Li (邸乃力), Ma Xiao (马骁), Kou Zhi-Qi (寇志起), Luo Zhi (罗志), Cheng Zhao-Hua (成昭华). Chin. Phys. B, 2003, 12(7): 789-791.
No Suggested Reading articles found!