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Chin. Phys. B, 2018, Vol. 27(8): 088201    DOI: 10.1088/1674-1056/27/8/088201
INTERDISCIPLINARY PHYSICS AND RELATED AREAS OF SCIENCE AND TECHNOLOGY Prev   Next  

Size effect of Si particles on the electrochemical performances of Si/C composite anodes

Bonan Liu(刘柏男)1,2, Hao Lu(陆浩)1,2, Geng Chu(褚赓)3, Fei Luo(罗飞)4, Jieyun Zheng(郑杰允)1, Shimou Chen(陈仕谋)3, Hong Li(李泓)1,2
1 Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China;
2 School of Physical Sciences, University of Chinese Academy of Sciences, Beijing 100049, China;
3 Key Laboratory of Green Process Engineering, State Key Laboratory of Multiphase Complex Systems, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China;
4 Tianmu Energy Anode Material Ltd. Co., Changzhou 213300, China
Abstract  

A series of Si/C composites were fabricated based on pitch and Si powders with particle sizes of 30, 100, 500, and 3000 nm. The size effects of the Si particles in the Si/C composites were investigated for lithium-ion battery anodes. The nanoscale Si and Si/C composites exhibited good capacity retentions. Scanning electron microscopy showed that exterior and interior cracks emerging owing to volume expansion as well as parasitic reactions with the electrolyte could well explain the performance failure.

Keywords:  silicon-carbon composite      solid-electrolyte interphase      size effect      anode      volume expansion  
Received:  29 April 2018      Revised:  24 May 2018      Accepted manuscript online: 
PACS:  82.47.Aa (Lithium-ion batteries)  
  65.40.gk (Electrochemical properties)  
  82.45.Fk (Electrodes)  
  62.23.Pq (Composites (nanosystems embedded in a larger structure))  
Fund: 

Project supported from the “Strategic Priority Research Program” of the Chinese Academy of Sciences (Grant No. XDA09010102).

Corresponding Authors:  Hong Li     E-mail:  hli@iphy.ac.cn

Cite this article: 

Bonan Liu(刘柏男), Hao Lu(陆浩), Geng Chu(褚赓), Fei Luo(罗飞), Jieyun Zheng(郑杰允), Shimou Chen(陈仕谋), Hong Li(李泓) Size effect of Si particles on the electrochemical performances of Si/C composite anodes 2018 Chin. Phys. B 27 088201

[1] Bridel J S, Azaïs T, Morcrette M, Tarascon J M and Larcher D 2010 Chem. Mater. 22 1229
[2] Kierzek K, Machnikowski J and Béguin F 2014 J. Appl. Electrochem. 45 1
[3] Luo F, Liu B, Zheng J Y, Chu G, Zhong K F, Li H, Huang X J and Chen L Q 2015 J. Electrochem. Soc. 162 A2509
[4] Flandrois S and Simon B 1999 Carbon 37 165
[5] Xu K 2004 Chem. Rev. 104 4303
[6] Hatchard T D and Dahn J R 2004 J. Electrochem. Soc. 151 A838
[7] Li J and Dahn J R 2007 J. Electrochem. Soc. 154 A156
[8] Pereira-Nabais C, Światowska J, Chagnes A, Ozanam F, Gohier A, Tran-Van P, Cojocaru C S, Cassir M and Marcus P 2013 Appl. Surf. Sci. 266 5
[9] Philippe B, Dedryv'ere R, Allouche J, Lindgren F, Gorgoi M, Rensmo H, Gonbeau D and Edström K 2012 Chem. Mater. 24 1107
[10] He Y, Yu X Q, Li G, Wang R, Li H, Wang Y L, Gao H J and Huang X J 2012 J. Power Sources 16 131
[11] McDowell M T, Lee S W, Nix W D and Cui Y 2013 Adv. Mater. 25 4966
[12] Obrovac M N and Chevrier V L 2014 Chem. Rev. 114 11444
[13] Zheng J Y, Zheng H, Wang R, Ben L B, Lu W, Chen L W, Chen L Q and Li H 2014 Phys. Chem. Chem. Phys. 16 13229
[14] Luo F, Chu G, Xia X X, Liu B N, Zheng J Y, Li J J, Li H, Gu C Z and Chen L Q 2015 Nanoscale 7 7651
[15] Dupre N, Moreau P, De Vito E, Quazuguel L, Boniface M, Bordes A, Rudisch C, Bayle-Guillemaud P and Guyomard D 2016 Chem. Mater. 28 2557
[16] Nguyen D T, Kang J, Nam K M, Paik Y and Song S W 2016 J. Power Sources 303 150
[17] Holzapfel M, Buqa H, Krumeich F, Novák P, Petrat F M and Veit C 2005 Electrochem. Solid State Lett. 8 A516
[18] Terranova M L, Orlanducci S, Tamburri E, Guglielmotti V and Rossi M 2014 J. Power Sources 246 167
[19] Zhao K, Pharr M, Wan Q, Wang W L, Kaxiras E, Vlassak J J and Suo Z G 2012 J. Electrochem. Soc. 159 A238
[20] Ma Z, Li T, Huang Y L, Liu J, Zhou Y and Xue D 2013 RSC Adv. 3 7398
[21] Zhao K, Pharr M, Cai S, Vlassak J J and Suo Z G 2011 J. Am. Ceram. Soc. 94 226
[22] Huang S, Fan F, Li J, Zhang S and Zhu T 2013 Acta Mater. 61 4354
[23] Kalnaus S, Rhodes K and Daniel C 2011 J. Power Sources 196 8116
[24] Liu X H, Zhong L, Huang S, Mao S X, Zhu T and Huang J Y 2012 ACS Nano 6 1522
[25] McDowell M T, Lee S W, Harris J T, Korgel B A, Wang C, Nix W D and Cui Y 2013 Nano Lett. 13 758
[26] Li H, Wang Z X, Huang X J and Chen L Q 2008 Physics 37 416 (in Chinese)
[27] Li H, Huang X J, Chen L Q, Wu Z G and Liang Y 1999 Electrochem. Solid State Lett. 2 547
[28] Lu H, Liu B N, Chu G, Zheng J Y, Luo F, Qiu X P, Li H, Liu F, Feng S N, Chen W, Li H and Chen L Q 2016 Energy Storage Science and Technology 5 109
[29] Zhang L Q, Liu X H, Liu Y, Huang S, Zhu T, Gui L, Mao S X, Ye Z Z, Wang C M, Sullivan J P and Huang J Y 2011 ACS Nano 5 4800
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