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Chin. Phys. B, 2015, Vol. 24(3): 036401    DOI: 10.1088/1674-1056/24/3/036401
CONDENSED MATTER: STRUCTURAL, MECHANICAL, AND THERMAL PROPERTIES Prev   Next  

Structural phase transitions of tellurium nanoplates under pressure

Li Chaoa, Arfan Bukhtiarb, Shen Xia, Kong Pan-Pana, Wang Wei-Penga, Zhao Hao-Feia, Yao Yuana, Zou Bing-Suob, Li Yan-Chunc, Li Xiao-Dongc, Liu Jingc, Jin Chang-Qinga, Yu Ri-Chenga
a Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China;
b Beijing Key Laboratory of Nanophotonics and Ultrafine Optoelectronic Systems, Beijing Institute of Technology, Beijing 100081, China;
c Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100039, China
Abstract  

In situ high-pressure angle dispersive x-ray diffraction experiments using synchrotron radiation on Te nanoplates were carried out with a diamond anvil cell at room temperature. The results show that Te-I with a trigonal structure transforms to triclinic Te-Ⅱ at about 4.9 GPa, Te-Ⅱ transforms to monoclinic Te-Ⅲ at about 8.0 GPa, Te-Ⅲ turns to rhombohedral Te-IV at about 23.8 GPa, and Te-IV changes to body centered cubic Te-V at 27.6 GPa. The bulk moduli B0 of Te nanoplates are higher than those of Te bulk materials.

Keywords:  tellurium nanoplates      phase transition      high pressure  
Received:  05 October 2014      Revised:  10 December 2014      Accepted manuscript online: 
PACS:  64.70.Nd (Structural transitions in nanoscale materials)  
  61.05.cf (X-ray scattering (including small-angle scattering))  
  64.60.-i (General studies of phase transitions)  
Fund: 

Project supported by the State Key Development Program for Basic Research of China (Grant No. 2012CB932302) and the National Natural Science Foundation of China (Grant Nos. 10974235 and 11174336).

Corresponding Authors:  Yu Ri-Cheng     E-mail:  rcyu@aphy.iphy.ac.cn

Cite this article: 

Li Chao, Arfan Bukhtiar, Shen Xi, Kong Pan-Pan, Wang Wei-Peng, Zhao Hao-Fei, Yao Yuan, Zou Bing-Suo, Li Yan-Chun, Li Xiao-Dong, Liu Jing, Jin Chang-Qing, Yu Ri-Cheng Structural phase transitions of tellurium nanoplates under pressure 2015 Chin. Phys. B 24 036401

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