An optimized, sensitive and stable reduced graphene oxide-gold nanoparticle-luminol-H2O2 chemiluminescence system and its potential analytical application

doi:10.1088/1674-1056/23/4/048103

Abstract The chemiluminescence (CL) performance of luminol is improved using reduced graphene oxide/gold nanoparticle (rGO-AuNP) nano-composites as catalyst. To prepare this catalyst, we propose a linker free, one-step method to in-situ synthesize rGO-AuNP nano-composites. Various measurements are utilized to characterize the resulting rGO-AuNP samples, and it is revealed that rGO could improve the stability and conductivity. Furthermore, we investigate the CL signals of luminal catalyzed by rGO-AuNP. Afterwards, the size effect of particle and the assisted enhancement effect of rGO are studied and discussed in detail. Based on the discussion, an optimal, sensitive and stable rGO-AuNP-luminon-H₂O₂ CL system is proposed. Finally, we utilize the system as a sensor to detect hydrogen peroxide and organic compounds containing amino, hydroxyl, or thiol groups. The CL system might provide a more attractive platform for various analytical devices with CL detection in the field of biosensors, bioassays, and immunosensors.

Keywords: graphene nanoparticles chemiluminescence biosensers

Received: 12 September 2013
Revised: 30 October 2013
Accepted manuscript online:

PACS:	81.05.ue	(Graphene)
	78.67.Bf	(Nanocrystals, nanoparticles, and nanoclusters)
	78.60.Ps	(Chemiluminescence)
	87.85.fk	(Biosensors)

Fund: Project supported by the National Key Basic Research Program, China (Grant Nos. 2011CB932700 and 2011CB932703), the National Natural Science Foundation of China (Grant Nos. 61378073, 61335006, 91123025, and 61077044), and the Beijing Natural Science FundProject, China (Grant No. 4132031).

Corresponding Authors: He Da-Wei, Zhang Xi-Qing
E-mail: dwhe@bjtu.edu.cn;xqzhang@bjtu.edu.cn

About author: 81.05.ue; 78.67.Bf; 78.60.Ps; 87.85.fk

Cite this article:

Wang Wen-Shuo (王闻硕), He Da-Wei (何大伟), Wang Ji-Hong (王继红), Duan Jia-Hua (段嘉华), Peng Hong-Shang (彭洪尚), Wu Hong-Peng (吴洪鹏), Fu Ming (富鸣), Wang Yong-Sheng (王永生), Zhang Xi-Qing (张希清) An optimized, sensitive and stable reduced graphene oxide-gold nanoparticle-luminol-H₂O₂ chemiluminescence system and its potential analytical application 2014 Chin. Phys. B 23 048103

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An optimized, sensitive and stable reduced graphene oxide-gold nanoparticle-luminol-H2O2 chemiluminescence system and its potential analytical application

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An optimized, sensitive and stable reduced graphene oxide-gold nanoparticle-luminol-H₂O₂ chemiluminescence system and its potential analytical application