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Chin. Phys. B, 2012, Vol. 21(3): 037202    DOI: 10.1088/1674-1056/21/3/037202
CONDENSED MATTER: ELECTRONIC STRUCTURE, ELECTRICAL, MAGNETIC, AND OPTICAL PROPERTIES Prev   Next  

Adsorption behavior of iron phthalocyanine on a Ag(110) surface

Wu Ke(吴珂), Huang Qi-Huan(黄齐晅), Zhang Han-Jie(张寒洁), Liao Qing(廖清), and He Pi-Mo(何丕模)
Physics Department, Zhejiang University, Hangzhou 310027, China
Abstract  An investigation on the growth behavior of FePc on a Ag (110) surface is carried out by using scanning tunneling microscopy (STM). At an FePc coverage of 3.5 ML, an ordered superstructure (densely packed) with a lateral shift is observed. The densely packed superstructure can be attributed to the substrate commensuration and the intermolecular van der Waals attractive interaction. The in-plane lateral shift in the superphase is specifically along the direction of [110] azimuth. The results provide a new perspective to understanding the intermolecular and the molecule-substrate interactions.
Keywords:  organic semiconductor      scanning tunneling microscopy      lateral shift      intermolecular interaction  
Received:  12 July 2011      Revised:  11 October 2011      Accepted manuscript online: 
PACS:  72.80.Le (Polymers; organic compounds (including organic semiconductors))  
  34.20.Gj (Intermolecular and atom-molecule potentials and forces)  
  34.35.+a (Interactions of atoms and molecules with surfaces)  
  87.64.Dz (Scanning tunneling and atomic force microscopy)  
Fund: Project supported by the National Natural Science Foundation of China (Grant Nos. 60506019, 10674118, and 10774129) and the Chinese Universities Scientific Fund.
Corresponding Authors:  He Pi-Mo,phypmhe@zju.edu.cn     E-mail:  phypmhe@zju.edu.cn

Cite this article: 

Wu Ke(吴珂), Huang Qi-Huan(黄齐晅), Zhang Han-Jie(张寒洁), Liao Qing(廖清), and He Pi-Mo(何丕模) Adsorption behavior of iron phthalocyanine on a Ag(110) surface 2012 Chin. Phys. B 21 037202

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