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Acta Physica Sinica (Overseas Edition), 1996, Vol. 5(9): 692-699    DOI: 10.1088/1004-423X/5/9/007
CONDENSED MATTER: STRUCTURAL, MECHANICAL, AND THERMAL PROPERTIES Prev   Next  

A POSSIBLE WAY TO MEASURE LITHIUM ION DIFFUSION COEFFICIENT FOR Li INSERTION THIN FILM WITH UNKNOWN Li COMPOSITION: APPLICATION TO Li$\alpha$CoO2 and WO3

WEN SHI-JIE (文世杰)a, CHEN LI-QUAN (陈立泉)b
a Energy & Environment Division, Lawrence Berkeley Laboratory, 1 Cyclotron Road, Berkeley, CA 94720, USA; b Institute of Physics, Academia Sinica, Beijing 100080, China
Abstract  In this paper, a new experimental method of lithium ion diffusion coefficient measurement for lithium intercalation thin film material is presented. This exper-imental method is feasible and can be applied to thin films with unknown lithium composition such as Li$\alpha$CoO2 etc. To check its validity, we used the impedance spec-troscopy method to make a verification on the WO3 thin film sample with known lithium composition.
Received:  20 February 1995      Revised:  09 March 1996      Accepted manuscript online: 
PACS:  66.30.H- (Self-diffusion and ionic conduction in nonmetals)  
  68.55.Nq (Composition and phase identification)  
  82.45.Mp (Thin layers, films, monolayers, membranes)  
  82.47.Aa (Lithium-ion batteries)  

Cite this article: 

WEN SHI-JIE (文世杰), CHEN LI-QUAN (陈立泉) A POSSIBLE WAY TO MEASURE LITHIUM ION DIFFUSION COEFFICIENT FOR Li INSERTION THIN FILM WITH UNKNOWN Li COMPOSITION: APPLICATION TO Li$\alpha$CoO2 and WO3 1996 Acta Physica Sinica (Overseas Edition) 5 692

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