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Pressure-induced phase transition of B-type Y2O3 |
| Qian Zhang(张倩)1, Xiang Wu(巫翔)2, Shan Qin(秦善)3 |
1 Gemological Institute, China University of Geosciences, Wuhan 430074, China;
2 State Key Laboratory of Geological Processes and Mineral Resources, China University of Geosciences, Wuhan 430074, China;
3 Key Laboratory of Orogenic Belts and Crustal Evolution, Ministry of Education & School of Earth and Space Sciences, Peking University, Beijing 100871, China |
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Abstract The synthesized monoclinic (B-type) phase of Y2O3 has been investigated by in situ angle-dispersive x-ray diffraction in a diamond anvil cell up to 44 GPa at room temperature. A phase transition occurs from monoclinic (B-type) to hexagonal (A-type) phase at 23.5 GPa and these two phases coexist even at the highest pressure. Parameters of isothermal equation of state are V0=69.0(1) Å3, K0=159(3) GPa, K0'=4 (fixed) for the B-type phase and V0=67.8(2) Å3, K0=156(3) GPa, K0'=4 (fixed) for the A-type phase. The structural anisotropy increases with increasing pressure for both phases.
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Received: 03 May 2017
Revised: 15 May 2017
Accepted manuscript online:
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PACS:
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07.35.+k
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(High-pressure apparatus; shock tubes; diamond anvil cells)
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61.05.cp
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(X-ray diffraction)
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91.60.Hg
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(Phase changes)
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| Fund: Project supported by the National Natural Science Foundation of China (Grant Nos. U1232204 and 41502029) and China Postdoctoral Science Foundation (Grant No. 2015M580679). |
Corresponding Authors:
Qian Zhang
E-mail: qianzhang@cug.edu.cn
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Cite this article:
Qian Zhang(张倩), Xiang Wu(巫翔), Shan Qin(秦善) Pressure-induced phase transition of B-type Y2O3 2017 Chin. Phys. B 26 090703
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