Exploring the compression behavior of HP-BiNbO4 under high pressure

doi:10.1088/1674-1056/26/11/116202

Abstract In the present work, a third form, the so-called HP-BiNbO₄ synthesized at high pressure and high temperature is investigated with the in-situ angle-dispersive x-ray diffraction (ADXRD) measurements under high pressure. We explore the compression behavior and phase stability of HP-BiNbO₄. The structure of HP-BiNbO₄ is first determined. The x-ray diffraction data reveal that the structure HP-BiNbO₄ is stable under pressures up to 24.1 GPa. The ADXRD data yield a bulk modulus K_o=185 (7) GPa with a pressure derivative K_o'=2.9 (0.8). Furthermore, the data are compared with those of other ABO₄ compounds. The results show that the bulk modulus of HP-BiNbO₄ (about 185 GPa) is slightly higher than that of tetragonal BiVO₄ and significantly greater than those of the tungstates and molybdates.

Keywords: high pressure BiNbO₄ x-ray diffraction bulk modulus

Received: 22 May 2017
Revised: 13 August 2017
Accepted manuscript online:

PACS:	62.50.-p	(High-pressure effects in solids and liquids)
	61.05.cp	(X-ray diffraction)
	61.50.Ks	(Crystallographic aspects of phase transformations; pressure effects)
	81.05.Je	(Ceramics and refractories (including borides, carbides, hydrides, nitrides, oxides, and silicides))

Fund: Project supported by the National Natural Science Foundation of China (Grant Nos. 51472171 and 11427810) and the Chinese Academy of Sciences (Grant Nos. KJCX2-SW-NO3 and KJCX2-SW-N20).

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Yin-Juan Liu(刘银娟), Jia-Wei Zhang(张佳威), Duan-Wei He(贺端威), Chao Xu(许超), Qi-Wei Hu(胡启威), Lei Qi(戚磊), A-Kun Liang(梁阿坤) Exploring the compression behavior of HP-BiNbO₄ under high pressure 2017 Chin. Phys. B 26 116202

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Exploring the compression behavior of HP-BiNbO4 under high pressure

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Exploring the compression behavior of HP-BiNbO₄ under high pressure