Fabrication and temperature-dependent photoluminescence spectra of Zn-Cu-In-S quaternary nanocrystals

doi:10.1088/1674-1056/23/11/117804

Abstract

A series of Zn-Cu-In-S nanocrystals (ZCIS NCs) are prepared and the optical properties of the ZCIS NCs are tuned by adjusting the reaction time. It is interesting to observe that the temperature-dependent photoluminescence (PL) spectra of the ZCIS NCs show a redshift with decreasing intensity at low temperature (50-280 K) and a blueshift at high temperature (318-403 K). The blueshift can be explained by the thermally active phonon-assisted tunneling from the excited states of the low-energy emission band to the excited states of the high-energy emission band.

Keywords: temperature-dependent photoluminescence photoluminescence lifetime quaternary nanocrystals white light emitting device

Received: 21 March 2014
Revised: 09 May 2014
Accepted manuscript online:

PACS:	78.67.Bf	(Nanocrystals, nanoparticles, and nanoclusters)
	78.55.-m	(Photoluminescence, properties and materials)
	78.40.-q	(Absorption and reflection spectra: visible and ultraviolet)
	78.40.Fy	(Semiconductors)

Fund:

Project supported by the National Natural Science Foundation of China (Grand Nos. 60907021, 60977035, and 60877029) and the Natural Science Foundation of Tianjin, China (Grant No. 11JCYBJC00300).

Corresponding Authors: Zhang Xiao-Song
E-mail: zhangxiaosong022@126.com

Cite this article:

Liu Xiao-Juan (刘晓娟), Zhang Xiao-Song (张晓松), Li Lan (李岚), Wang Xue-Liang (王雪亮), Yuan Lin-Lin (苑琳琳) Fabrication and temperature-dependent photoluminescence spectra of Zn-Cu-In-S quaternary nanocrystals 2014 Chin. Phys. B 23 117804

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Fabrication and temperature-dependent photoluminescence spectra of Zn-Cu-In-S quaternary nanocrystals

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