Review of magnetocaloric effect in perovskite-type oxides

doi:10.1088/1674-1056/22/5/057501

Abstract We survey the magnetocaloric effect in perovskite-type oxides (including doped ABO₃-type manganese oxides, A₃B₂O₇-type two-layered perovskite oxides, and A2B'B''O₆-type ordered double-perovskite oxides). Magnetic entropy changes larger than those of gadolinium can be observed in polycrystalline La_1-xCa_xMnO₃ and alkali-metal (Na or K) doped La_0.8Ca_0.2MnO₃ perovskite-type manganese oxides. The large magnetic entropy change produced by an abrupt reduction of magnetization is attributed to the anomalous thermal expansion at the Curie temperature. Considerable magnetic entropy changes can also be observed in two-layered perovskites La_1.6Ca_1.4Mn₂O₇ and La_2.5-xK_0.5+xMn₂O_7+δ (0 < x < 0.5), and double-perovskite Ba₂Fe_1+xMo_1-xO₆ (0 ≤ x ≤ 0.3) near their respective Curie temperatures. Compared with rare earth metals and their alloys, the perovskite-type oxides are lower in cost, and they exhibit higher chemical stability and higher electrical resistivity, which together favor lower eddy-current heating. They are potential magnetic refrigerants at high temperatures, especially near room temperature.

Keywords: perovskite-type oxides magnetocaloric effect magnetic entropy change magnetic phase transition

Received: 22 February 2013
Accepted manuscript online:

PACS:	75.30.Sg	(Magnetocaloric effect, magnetic cooling)
	75.50.Bb	(Fe and its alloys)

Fund: Project supported by the National Natural Science Foundation of China (Grant No. 11174132), the National Basic Research Program of China (Grant Nos. 2011CB922102 and 2012CB932304), and the Priority Academic Program Development of Jiangsu Higher Education Institutions, China.

Corresponding Authors: Zhong Wei
E-mail: wzhong@nju.edu.cn

Cite this article:

Zhong Wei (钟伟), Au Chak-Tong (区泽棠), Du You-Wei (都有为) Review of magnetocaloric effect in perovskite-type oxides 2013 Chin. Phys. B 22 057501

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