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Chin. Phys. B, 2022, Vol. 31(10): 107307    DOI: 10.1088/1674-1056/ac8e9f
Special Issue: TOPICAL REVIEW — Celebrating 30 Years of Chinese Physics B
TOPICAL REVIEW—Celebrating 30 Years of Chinese Physics B Prev   Next  

Recent advances of interface engineering in inverted perovskite solar cells

Shiqi Yu(余诗琪)1,2, Zhuang Xiong(熊壮)1,2, Zhenhan Wang(王振涵)1,2, Haitao Zhou(周海涛)1,2, Fei Ma(马飞)1,2, Zihan Qu(瞿子涵)1,2, Yang Zhao(赵洋)1,2, Xinbo Chu(楚新波)1,2, and Jingbi You(游经碧)1,2,†
1. Key Laboratory of Semiconductor Materials Science, Institute of Semiconductors, Chinese Academy of Sciences, Beijing 100083, China;
2. Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, China
Abstract  Perovskite solar cells (PSCs) have witnessed great achievement in the past decade. Most of previous researches focus on the n—i—p structure of PSCs with ultra-high efficiency. While the n—i—p devices usually used the unstable charge transport layers, such as the hygroscopic doped spiro-OMeTAD, which affect the long-term stability. The inverted device with the p—i—n structure owns better stability when using stable undoped organic molecular or metal oxide materials. There are significant progresses in inverted PSCs, most of them related to charge transport or interface engineering. In this review, we will mainly summarize the inverted PSCs progresses related to the interface engineering. After that, we prospect the future direction on inverted PSCs.
Keywords:  inverted perovskite solar cells      charge transport layer      interface modification      defect passivation  
Received:  02 August 2022      Revised:  28 August 2022      Accepted manuscript online: 
PACS:  73.40.Lq (Other semiconductor-to-semiconductor contacts, p-n junctions, and heterojunctions)  
  68.65.-k (Low-dimensional, mesoscopic, nanoscale and other related systems: structure and nonelectronic properties)  
  68.35.-p (Solid surfaces and solid-solid interfaces: structure and energetics)  
  81.05.Hd (Other semiconductors)  
Fund: This work was supported by the National Natural Science Foundation of China (Grant No. 61925405) and the National Key Research and Development Program of China (Grant No. 2020YFB1506400).
Corresponding Authors:  Jingbi You     E-mail:  jyou@semi.ac.cn

Cite this article: 

Shiqi Yu(余诗琪), Zhuang Xiong(熊壮), Zhenhan Wang(王振涵), Haitao Zhou(周海涛), Fei Ma(马飞), Zihan Qu(瞿子涵), Yang Zhao(赵洋), Xinbo Chu(楚新波), and Jingbi You(游经碧) Recent advances of interface engineering in inverted perovskite solar cells 2022 Chin. Phys. B 31 107307

[1] Burschka J, Pellet N, Moon S J, Humphry-Baker R, Gao P, Nazeeruddin M K and Grätzel M 2013 Nature 499 316
[2] Dong Q, Fang Y, Shao Y, Mulligan P, Qiu J, Cao L and Huang J 2015 Science 347 967
[3] Jeon N J, Noh J H, Kim Y C, Yang W S, Ryu S and Seok S I 2014 Nat. Mater. 13 897
[4] Liu M, Johnston M B and Snaith H J 2013 Nature 501 395
[5] Mcmeekin D P, Sadoughi G, Rehman W, Eperon G E, Saliba M, Hörantner M T, Haghighirad A, Sakai N, Korte L, Rech B, Johnston M B, Herz L M and Snaith H J 2016 Science 351 151
[6] Meng L, You J, Guo T F and Yang Y 2016 Accounts of Chemical Research 49 155
[7] Abdi-Jalebi M, Andaji-Garmaroudi Z, Cacovich S, Stavrakas C, Philippe B, Richter J M, Alsari M, Booker E P, Hutter E M, Pearson A J, Lilliu S, Savenije T J, Rensmo H, Divitini G, Ducati C, Friend R H and Stranks S D 2018 Nature 555 497
[8] Bi D, Yi C, Luo J, Döcoppet J D, Zhang F, Zakeeruddin Shaik M, Li X, Hagfeldt A and Grätzel M 2016 Nat. Energy 1 16142
[9] Dai Q, Luo C, Wang X, Gao F, Jiang X and Zhao Q 2022 Chin. Phys. B 31 037303
[10] Jiang Q, Zhao Y, Zhang X, Yang X, Chen Y, Chu Z, Ye Q, Li X, Yin Z and You J 2019 Nat. Photon. 13 460
[11] Ke W, Fang G, Wan J, Tao H, Liu Q, Xiong L, Qin P, Wang J, Lei H, Yang G, Qin M, Zhao X and Yan Y 2015 Nat. Commun. 6 6700
[12] Kojima A, Teshima K, Shirai Y and Miyasaka T 2009 Journal of the American Chemical Society 131 6050
[13] Lee M M, Teuscher J, Miyasaka T, Murakami T N and Snaith H J 2012 Science 338 643
[14] Min H, Lee D Y, Kim J, Kim G, Lee K S, Kim J, Paik M J, Kim Y K, Kim K S, Kim M G, Shin T J and Il Seok S 2021 Nature 598 444
[15] Qu Z, Ma F, Zhao Y, Chu X, Yu S and You J 2021 Chin. Phys. Lett. 38 107801
[16] Tan H, Jain A, Voznyy O, Lan X, Arquer F P G D, Fan J Z, Quintero-Bermudez R, Yuan M, Zhang B, Zhao Y, Fan F, Li P, Quan L N, Zhao Y, Lu Z H, Yang Z, Hoogland S and Sargent E H 2017 Science 355 722
[17] Yu Zhan W C, Fu Yang and Li Y 2021 Chin. Phys. B 30 88803
[18] Zheng X, Chen B, Dai J, Fang Y, Bai Y, Lin Y, Wei H, Zeng Xiao C and Huang J 2017 Nat. Energy 2 17102
[19] https://www.nrel.gov/pv/assets/pdfs/best-research-cell-efficiencies-rev220126.pdf
[20] Baikie T, Fang Y, Kadro J M, Schreyer M, Wei F, Mhaisalkar S G, Graetzel M and White T J 2013 Journal of Materials Chemistry A 1 5628
[21] Berhe T A, Su W N, Chen C H, Pan C J, Cheng J H, Chen H M, Tsai M C, Chen L Y, Dubale A A and Hwang B J 2016 Energy & Environmental Science 9 323
[22] Saparov B and Mitzi D B 2016 Chemical Reviews 116 4558
[23] Stranks S D and Snaith H J 2015 Nat. Nanotech. 10 391
[24] Djurišić A B, Liu F Z, Tam H W, Wong M K, Ng A, Surya C, Chen W and He Z B 2017 Progress in Quantum Electronics 53 1
[25] Park J H, Seo J, Park S, Shin S S, Kim Y C, Jeon N J, Shin H W, Ahn T K, Noh J H, Yoon S C, Hwang C S and Seok S I 2015 Adv. Mater. 27 4013
[26] Jeng J Y, Chiang Y F, Lee M H, Peng S R, Guo T F, Chen P and Wen T C 2013 Adv. Mater. 25 3727
[27] Li Z, Li B, Wu X, Sheppard S A, Zhang S, Gao D, Long N J and Zhu Z 2022 Science 376 416
[28] Liu T, Chen K, Hu Q, Zhu R and Gong Q 2016 Advanced Energy Materials 6 1600457
[29] Yang X, Luo D, Xiang Y, Zhao L, Anaya M, Shen Y, Wu J, Yang W, Chiang Y H, Tu Y, Su R, Hu Q, Yu H, Shao G, Huang W, Russell T P, Gong Q, Stranks S D, Zhang W and Zhu R 2021 Adv. Mater. 33 2006435
[30] Bagheri Z, Matteocci F, Lamanna E, Di Girolamo D, Marrani A G, Zanoni R, Di Carlo A and Moshaii A 2020 Solar Energy Materials and Solar Cells 215 110606
[31] Luo D, Yang W, Wang Z, Sadhanala A, Hu Q, Su R, Shivanna R, Trindade G F, Watts J F, Xu Z, Liu T, Chen K, Ye F, Wu P, Zhao L, Wu J, Tu Y, Zhang Y, Yang X, Zhang W, Friend R H, Gong Q, Snaith H J and Zhu R 2018 Science 360 1442
[32] Wang H, Song Y, Kang Y, Dang S, Feng J and Dong Q 2020 Journal of Materials Chemistry A 8 7309
[33] Li X, Zhang W, Guo X, Lu C, Wei J and Fang J 2022 Science 375 434
[34] Degani M, An Q, Albaladejo-Siguan M, Hofstetter Y J, Cho C, Paulus F, Grancini G and Vaynzof Y 2021 Science Advances 7 eabj7930
[35] Zhou Q, Qiu J, Wang Y, Yu M, Liu J and Zhang X 2021 ACS Energy Letters 6 1596
[36] Chen S, Dai X, Xu S, Jiao H, Zhao L and Huang J 2021 Science 373 902
[37] Wu S, Zhang J, Li Z, Liu D, Qin M, Cheung S H, Lu X, Lei D, So S K, Zhu Z and Jen A K Y 2020 Joule 4 1248
[38] Li X, Liu X, Wang X, Zhao L, Jiu T and Fang J 2015 Journal of Materials Chemistry A 3 15024
[39] Li X, Wang Y C, Zhu L, Zhang W, Wang H Q and Fang J 2017 ACS Applied Materials & Interfaces 9 31357
[40] Li J, Zhao M, Zhao C, Jian H, Wang N, Yao L, Huang C, Zhao Y and Jiu T 2019 ACS Applied Materials & Interfaces 11 2626
[41] Li S, He B, Xu J, Lu H, Jiang J, Zhu J, Kan Z, Zhu L and Wu F 2020 Nanoscale 12 3686
[42] Li X, Zhang W, Guo X, Lu C, Wei J and Fang J 2022 Science 375 434
[43] Kim S Y, Cho S J, Byeon S E, He X and Yoon H J 2020 Advanced Energy Materials 10 2002606
[44] Magomedov A, Al-Ashouri A, Kasparavičius E, Strazdaite S, Niaura G, Jošt M, Malinauskas T, Albrecht S and Getautis V 2018 Advanced Energy Materials 8 1801892
[45] Metoki N, Liu L, Beilis E, Eliaz N and Mandler D 2014 Langmuir 30 6791
[46] Azmi R, Ugur E, Seitkhan A, Aljamaan F, Subbiah A S, Liu J, Harrison G T, Nugraha M I, Eswaran M K, Babics M, Chen Y, Xu F, Allen T G, Rehman A U, Wang C L, Anthopoulos T D, Schwingenschlogl U, De Bastiani M, Aydin E and De Wolf S 2022 Science 376 73
[47] Al-Ashouri A, Kohnen E, Li B, et al. 2020 Science 370 1300
[48] Al-Ashouri A, Magomedov A, Ross M, et al. 2019 Energy & Environmental Science 12 3356
[49] Gharibzadeh S, Fassl P, Hossain I M, Rohrbeck P, Frericks M, Schmidt M, Duong T, Khan M R, Abzieher T, Nejand B A, Schackmar F, Almora O, Feeney T, Singh R, Fuchs D, Lemmer U, Hofmann J P, Weber S a L and Paetzold U W 2021 Energy & Environmental Science 14 5875
[50] Levine I, Al-Ashouri A, Musiienko A, Hempel H, Magomedov A, Drevilkauskaite A, Getautis V, Menzel D, Hinrichs K, Unold T, Albrecht S and Dittrich T 2021 Joule 5 2915
[51] Aktas E, Phung N, Köbler H, González D A, Méndez M, Kafedjiska I, Turren-Cruz S H, Wenisch R, Lauermann I, Abate A and Palomares E 2021 Energy & Environmental Science 14 3976
[52] Liao Q, Wang Y, Zhang Z, Yang K, Shi Y, Feng K, Li B, Huang J, Gao P and Guo X 2022 Journal of Energy Chemistry 68 87
[53] Ullah A, Park K H, Nguyen H D, Siddique Y, Shah S F A, Tran H, Park S, Lee S I, Lee K K, Han C H, Kim K, Ahn S, Jeong I, Park Y S and Hong S 2022 Advanced Energy Materials 12 2103175
[54] Li L, Gibson E A, Qin P, Boschloo G, Gorlov M, Hagfeldt A and Sun L 2010 Advanced Materials 22 1759
[55] Manders J R, Tsang S W, Hartel M J, Lai T H, Chen S, Amb C M, Reynolds J R and So F 2013 Advanced Functional Materials 23 2993
[56] Liu S, Liu R, Chen Y, Ho S, Kim J H and So F 2014 Chemistry of Materials 26 4528
[57] Arumugam G M, Karunakaran S K, Liu C, Zhang C, Guo F, Wu S and Mai Y 2021 Nano Select 2 1081
[58] Docampo P, Ball J M, Darwich M, Eperon G E and Snaith H J 2013 Nat. Commun. 4 2761
[59] Wang T, Ding D, Zheng H, Wang X, Wang J, Liu H and Shen W 2019 Solar RRL 3 1900045
[60] Seo S, Park I J, Kim M, Lee S, Bae C, Jung H S, Park N G, Kim J Y and Shin H 2016 Nanoscale 8 11403
[61] Koushik D, Jošt M, Dučinskas A, Burgess C, Zardetto V, Weijtens C, Verheijen M A, Kessels W M M, Albrecht S and Creatore M 2019 Journal of Materials Chemistry C 7 12532
[62] Bai Y, Chen H, Xiao S, Xue Q, Zhang T, Zhu Z, Li Q, Hu C, Yang Y, Hu Z, Huang F, Wong K S, Yip H L and Yang S 2016 Advanced Functional Materials 26 2950
[63] Wang Q, Chueh C C, Zhao T, Cheng J, Eslamian M, Choy W C H and Jen A K Y 2017 ChemSusChem 10 3794
[64] Phung N, Verheijen M, Todinova A, Datta K, Verhage M, Al-Ashouri A, Köbler H, Li X, Abate A, Albrecht S and Creatore M 2022 ACS Applied Materials & Interfaces 14 2166
[65] Li Z, Jo B H, Hwang S J, Kim T H, Somasundaram S, Kamaraj E, Bang J, Ahn T K, Park S and Park H J 2019 Advanced Science 6 1802163
[66] Lian X, Chen J, Shan S, Wu G and Chen H 2020 ACS Applied Materials & Interfaces 12 46340
[67] Wang Y, Ju H, Mahmoudi T, Liu C, Zhang C, Wu S, Yang Y, Wang Z, Hu J, Cao Y, Guo F, Hahn Y B and Mai Y 2021 Nano Energy 88 106285
[68] Jung J W, Chueh C C and Jen A K Y 2015 Adv. Mater. 27 7874
[69] Yao K, Li F, He Q, Wang X, Jiang Y, Huang H and Jen A K Y 2017 Nano Energy 40 155
[70] Feng M, Wang M, Zhou H, Li W, Wang S, Zang Z and Chen S 2020 ACS Applied Materials & Interfaces 12 50684
[71] Chen W, Zhou Y, Chen G, Wu Y, Tu B, Liu F Z, Huang L, Ng A M C, Djurišić A B and He Z 2019 Advanced Energy Materials 9 1803872
[72] Xu J, Buin A, Ip A H, Li W, Voznyy O, Comin R, Yuan M, Jeon S, Ning Z, Mcdowell J J, Kanjanaboos P, Sun J P, Lan X, Quan L N, Kim D H, Hill I G, Maksymovych P and Sargent E H 2015 Nat. Commun. 6 7081
[73] Sun X, Ji L Y, Chen W W, Guo X, Wang H H, Lei M, Wang Q and Li Y F 2017 Journal of Materials Chemistry A 5 20720
[74] Shao Y, Xiao Z, Bi C, Yuan Y and Huang J 2014 Nat. Commun. 5 5784
[75] Chen C, Zhang S, Wu S, Zhang W, Zhu H, Xiong Z, Zhang Y and Chen W 2017 RSC Advances 7 35819
[76] Li D, Kong W, Zhang H, Wang D, Li W, Liu C, Chen H, Song W, Gao F, Amini A, Xu B, Li S and Cheng C 2020 ACS Applied Materials & Interfaces 12 20103
[77] Chueh C C, Li C Z, Ding F, Li Z A, Cernetic N, Li X and Jen A K Y 2017 ACS Applied Materials & Interfaces 9 1136
[78] Yang D, Zhang X, Wang K, Wu C, Yang R, Hou Y, Jiang Y, Liu S and Priya S 2019 Nano Lett. 19 3313
[79] Wang J and Zhan X 2021 Accounts of Chemical Research 54 132
[80] Wang S, Chen H, Zhang J, Xu G, Chen W, Xue R, Zhang M, Li Y and Li Y 2019 Adv. Mater. 31 1903691
[81] Jiang Y, Wang J, Zai H, Ni D, Wang J, Xue P, Li N, Jia B, Lu H, Zhang Y, Wang F, Guo Z, Bi Z, Xie H, Wang Q, Ma W, Tu Y, Zhou H and Zhan X 2022 Journal of the American Chemical Society 144 5400
[82] Mann D S, Patil P, Kim D H, Kwon S N and Na S I 2020 Journal of Power Sources 477 228738
[83] Troughton J, Neophytou M, Gasparini N, Seitkhan A, Isikgor F H, Song X, Lin Y H, Liu T, Faber H, Yengel E, Kosco J, Oszajca M F, Hartmeier B, Rossier M, Lüchinger N A, Tsetseris L, Snaith H J, De Wolf S, Anthopoulos T D, Mcculloch I and Baran D 2020 Energy & Environmental Science 13 268
[84] Hu X, Liu C, Zhang Z, Jiang X F, Garcia J, Sheehan C, Shui L, Priya S, Zhou G, Zhang S and Wang K 2020 Advanced Science 7 2001285
[85] Brinkmann K O, Zhao J, Pourdavoud N, Becker T, Hu T, Olthof S, Meerholz K, Hoffmann L, Gahlmann T, Heiderhoff R, Oszajca M F, Luechinger N A, Rogalla D, Chen Y, Cheng B and Riedl T 2017 Nat. Commun. 8 13938
[86] Chen H, Teale S, Chen B, Hou Y, Grater L, Zhu T, Bertens K, Park S M, Atapattu H R, Gao Y, Wei M, Johnston A K, Zhou Q, Xu K, Yu D, Han C, Cui T, Jung E H, Zhou C, Zhou W, Proppe A H, Hoogland S, Laquai F, Filleter T, Graham K R, Ning Z and Sargent E H 2022 Nat. Photon. 16 352
[87] Lin R, Xu J, Wei M, Wang Y, Qin Z, Liu Z, Wu J, Xiao K, Chen B, Park S M, Chen G, Atapattu H R, Graham K R, Xu J, Zhu J, Li L, Zhang C, Sargent E H and Tan H 2022 Nature 603 73
[88] Yu Z, Yang Z, Ni Z, Shao Y, Chen B, Lin Y, Wei H, Yu Z J, Holman Z and Huang J 2020 Nat. Energy 5 657
[89] Lin Y H, Sakai N, Da P, Wu J, Sansom H C, Ramadan A J, Mahesh S, Liu J, Oliver R D J, Lim J, Aspitarte L, Sharma K, Madhu P K, Morales-Vilches A B, Nayak P K, Bai S, Gao F, Grovenor C R M, Johnston M B, Labram J G, Durrant J R, Ball J M, Wenger B, Stannowski B and Snaith H J 2020 Science 369 96
[90] Bai S, Da P, Li C, Wang Z, Yuan Z, Fu F, Kawecki M, Liu X, Sakai N, Wang J T W, Huettner S, Buecheler S, Fahlman M, Gao F and Snaith H J 2019 Nature 571 245
[91] Li D, Huang Y, Wang G, Lian Q, Shi R, Zhang L, Wang X, Gao F, Kong W, Xu B, Cheng C and Li S 2021 Journal of Materials Chemistry A 9 12746
[92] Caprioglio P, Cruz D S, Caicedo-Dávila S, Zu F, Sutanto A A, Peñe-Camargo F, Kegelmann L, Meggiolaro D, Gregori L, Wolff C M, Stiller B, Perdigón-Toro L, Köbler H, Li B, Gutierrez-Partida E, Lauermann I, Abate A, Koch N, De Angelis F, Rech B, Grancini G, Abou-Ras D, Nazeeruddin M K, Stolterfoht M, Albrecht S, Antonietti M and Neher D 2021 Energy & Environmental Science 14 4508
[93] Yang S, Dai J, Yu Z, Shao Y, Zhou Y, Xiao X, Zeng X C and Huang J 2019 Journal of the American Chemical Society 141 5781
[94] Wu W Q, Rudd P N, Wang Q, Yang Z and Huang J 2020 Adv. Mater. 32 2000995
[95] Li F, Deng X, Qi F, Li Z, Liu D, Shen D, Qin M, Wu S, Lin F, Jang S H, Zhang J, Lu X, Lei D, Lee C S, Zhu Z and Jen A K Y 2020 Journal of the American Chemical Society 142 20134
[96] Zhang F, Ye S, Zhang H, Zhou F, Hao Y, Cai H, Song J and Qu J 2021 Nano Energy 89 106370
[97] Tan S, Huang T, Yavuz I, Wang R, Yoon T W, Xu M, Xing Q, Park K, Lee D K, Chen C H, Zheng R, Yoon T, Zhao Y, Wang H C, Meng D, Xue J, Song Y J, Pan X, Park N G, Lee J W and Yang Y 2022 Nature 605 268
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