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Chin. Phys. B, 2022, Vol. 31(8): 087103    DOI: 10.1088/1674-1056/ac6edf

Tailored martensitic transformation and enhanced magnetocaloric effect in all-d-metal Ni35Co15Mn33Fe2Ti15 alloy ribbons

Yong Li(李勇)1,†, Liang Qin(覃亮)1, Hongguo Zhang(张红国)2, and Lingwei Li(李领伟)1
1 Key Laboratory of Novel Materials for Sensor of Zhejiang Province, College of Materials&Environmental Engineering, Hangzhou Dianzi University, Hangzhou 310018, China;
2 Faculty of Materials and Manufacturing, Key Laboratory of Advanced Functional Materials, Ministry of Education of China, Beijing University of Technology, Beijing 100124, China
Abstract  The crystal structure, martensitic transformation and magnetocaloric effect have been studied in all-$d$-metal Ni$_{35}$Co$_{15}$Mn$_{33}$Fe$_{2}$Ti$_{15}$ alloy ribbons with different wheel speeds (15 m/s (S15), 30 m/s (S30), and 45 m/s (S45)). All three ribbons crystalize in B2-ordered structure at room temperature with crystal constants of 5.893(2) Å, 5.898(4) Å, and 5.898(6) Å, respectively. With the increase of wheel speed, the martensitic transformation temperature decreases from 230 K to 210 K, the Curie temperature increases slightly from 371 K to 378 K. At the same time, magnetic entropy change ($\Delta S_{\rm m}$) is also enhanced, as well as refrigeration capacity ($RC$). The maximum $\Delta S_{\rm m}$ of 15.6(39.7) J/kg$\cdot$K and $RC$ of 85.5 (212.7) J/kg under $\Delta H = 20$ (50) kOe (1 ${\rm Oe}=79.5775$ A$\cdot$m$^{-1}$) appear in S45. The results indicate that the ribbons could be the candidate for solid-state magnetic refrigeration materials.
Keywords:  martensitic transformation      magnetocaloric effect      wheel speeds      all-d-metal Heusler ribbons  
Received:  04 March 2022      Revised:  07 May 2022      Accepted manuscript online:  12 May 2022
PACS:  71.15.Mb (Density functional theory, local density approximation, gradient and other corrections)  
  31.15.A- (Ab initio calculations)  
  71.20.-b (Electron density of states and band structure of crystalline solids)  
  75.20.En (Metals and alloys)  
Fund: Project supported by the National Natural Science Foundation of China (Grant Nos. 52001102 and 51771003).
Corresponding Authors:  Yong Li     E-mail:

Cite this article: 

Yong Li(李勇), Liang Qin(覃亮), Hongguo Zhang(张红国), and Lingwei Li(李领伟) Tailored martensitic transformation and enhanced magnetocaloric effect in all-d-metal Ni35Co15Mn33Fe2Ti15 alloy ribbons 2022 Chin. Phys. B 31 087103

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