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Chin. Phys. B, 2021, Vol. 30(9): 094208    DOI: 10.1088/1674-1056/ac11eb
ELECTROMAGNETISM, OPTICS, ACOUSTICS, HEAT TRANSFER, CLASSICAL MECHANICS, AND FLUID DYNAMICS Prev   Next  

Ultrabroadband mid-infrared emission from Cr2+:ZnSe-doped chalcogenide glasses prepared via hot uniaxial pressing and melt-quenching

Ke-Lun Xia(夏克伦)1, Guang Jia(贾光)1, Hao-Tian Gan(甘浩天)2,3, Yi-Ming Gui(桂一鸣)2,3, Xu-Sheng Zhang(张徐生)2,3, Zi-Jun Liu(刘自军)2,3,†, and Xiang Shen(沈祥)2,3
1 Ningbo Institute of Oceanography, Ningbo 315832, China;
2 Laboratory of Infrared Materials and Devices, Advanced Technology Research Institute, Ningbo University, Ningbo 315211, China;
3 Key Laboratory of Photoelectric Detection Materials and Devices of Zhejiang Province, Ningbo 315211, China
Abstract  We reported an ultrabroadband mid-infrared (MIR) emission in the range of 1800 nm-3100 nm at room temperature (RT) from a Cr2+:ZnSe-doped chalcogenide glasses (ChGs) and studied the emission-dependent properties on the doping methods. A series of Cr2+:ZnSe/As40S57Se3 (in unit wt.%) glass-ceramics were prepared by hot uniaxial pressing (HUP) and melt-quenching methods, respectively. The glass-ceramics with MIR emission bands greater than 1000 nm were successfully prepared by both methods. The effects of matrix glass composition and grain doping concentration on the optical properties of the samples were studied. The occurrence state, morphology of the grains, and the microscopic elemental distributions were characterized using x-ray diffraction (XRD), scanning electron microscope (SEM), and energy dispersive spectrometer (EDS) analyses.
Keywords:  mid-infrared emission      glass-ceramics      hot uniaxial pressing      melt-quenching  
Received:  11 June 2021      Revised:  02 July 2021      Accepted manuscript online:  07 July 2021
PACS:  42.70.Km (Infrared transmitting materials)  
  42.70.Hj (Laser materials)  
  42.70.-a (Optical materials)  
  81.05.Ea (III-V semiconductors)  
Fund: Project supported by the Key Research and Development Program of Zhejiang Province, China (Grant No. 2021C01025), the National Natural Science Foundation of China (Grant Nos. 61975086 and 61605095), the Zhejiang Provincial Natural Science Foundation of China (Grant No. LY19F050004), the National Key Research and Development Program of China (Grant No. 2016YFB0303803), the K. C. Wong Magna Fund at Ningbo University, and the Natural Science Foundation of Ningbo (Grant No. 202003N4180).
Corresponding Authors:  Zi-Jun Liu     E-mail:  liuzijun@nbu.edu.cn

Cite this article: 

Ke-Lun Xia(夏克伦), Guang Jia(贾光), Hao-Tian Gan(甘浩天), Yi-Ming Gui(桂一鸣), Xu-Sheng Zhang(张徐生), Zi-Jun Liu(刘自军), and Xiang Shen(沈祥) Ultrabroadband mid-infrared emission from Cr2+:ZnSe-doped chalcogenide glasses prepared via hot uniaxial pressing and melt-quenching 2021 Chin. Phys. B 30 094208

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