Self-assembly 2D plasmonic nanorice film for surface-enhanced Raman spectroscopy

doi:10.1088/1674-1056/abefc4

Abstract As an ultrasensitive sensing technology, the application of surface enhanced Raman spectroscopy (SERS) is one interesting topic of nano-optics, which has huge application prospectives in plenty of research fields. In recent years, the bottleneck in SERS application could be the fabrication of SERS substrate with excellent enhancement. In this work, a two-dimensional (2D) Ag nanorice film is fabricated by self-assembly method as a SERS substrate. The collected SERS spectra of various molecules on this 2D plasmonic film demonstrate quantitative detection could be performed on this SERS substrate. The experiment data also demonstrate this 2D plasmonic film consisted of anisotropic nanostructures has no obvious SERS polarization dependence. The simulated electric field distribution points out the SERS enhancement comes from the surface plasmon coupling between nanorices. And the SERS signals is dominated by molecules adsorbed at different regions of nanorice surface at various wavelengths, which could be a good near IR SERS substrate for bioanalysis. Our work not only enlarges the surface plasmon properties of metal nanostructure, but also exhibits the good application prospect in SERS related fields.

Keywords: surface plasmon surface-enhanced Raman spectroscopy (SERS) nanorice 2D plasmonic film

Received: 05 February 2021
Revised: 13 March 2021
Accepted manuscript online: 18 March 2021

PACS:	74.25.nd	(Raman and optical spectroscopy)
	78.30.-j	(Infrared and Raman spectra)
	36.20.Ng	(Vibrational and rotational structure, infrared and Raman spectra)

Fund: Project supported by the National Natural Science Foundation of China (Grant No. 11974067), Natural Science Foundation Project of CQ CSTC (Grant Nos. cstc2019jcyj-msxmX0145, cstc2019jcyj-bshX0042, and cstc2019jcyj-msxmX0828), and Sharing Fund of Chongqing University & Large-scale Equipment.

Corresponding Authors: Xiaonan Sun, Yingzhou Huang
E-mail: xnsun168@cqu.edu.cn;yzhuang@cqu.edu.cn

Cite this article:

Tingting Liu(柳婷婷), Chuanyu Liu(刘船宇), Jialing Shi(石嘉玲), Lingjun Zhang(张玲君), Xiaonan Sun(孙晓楠), and Yingzhou Huang(黄映洲) Self-assembly 2D plasmonic nanorice film for surface-enhanced Raman spectroscopy 2021 Chin. Phys. B 30 117301

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