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Chin. Phys. B, 2021, Vol. 30(3): 036501    DOI: 10.1088/1674-1056/abcf39

Low thermal expansion and broad band photoluminescence of Zr0.1Al1.9Mo2.9V0.1O12

Jun-Ping Wang(王俊平) 1,2,†, Qing-Dong Chen(陈庆东)1, Li-Gang Chen(陈立刚)1, Yan-Jun Ji(纪延俊)1, You-Wen Liu(刘友文)2, and Er-Jun Liang(梁二军)3
1 Shandong Engineering Research Center of Aeronautical Materials and Devices; Key Laboratory of Aeronautical Optoelectronic Materials and Devices, College of Aeronautical Engineering, Binzhou University, Binzhou 256603, China; 2 College of Science, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, China; 3 School of Physical Science & Engineering and Key Laboratory of Materials Physics of Ministry of Education, Zhengzhou University, Zhengzhou 450052, China
Abstract  A new material of Zr0.1Al1.9Mo2.9V0.1O12 is synthesized by the traditional solid state synthesis method. The phase transition, coefficient of thermal expansion, and luminescence properties of Zr0.1Al1.9Mo2.9V0.1O12 are explored with Raman spectrometer, dilatometer, and x-ray diffraction (XRD) diffractometer. The results show that the Zr0.1Al1.9Mo2.9V0.1O12 possesses the strong broad-band luminescence characteristics almost in the whole visible region. The sample is crystallized in a monoclinic structure group of P21/a (No. 14) crystallized at room temperature (RT). The crystal is changed from monoclinic to orthorhombic structure when the temperature increases to 463 K. The material has very low thermal expansion performance in a wide temperature range. Its excellent low thermal expansion and strong pale green light properties in a wide temperature range suggest its potential applications in light-emitting diode (LED) and other optoelectronic devices.
Keywords:  low thermal expansion      phase transition      x-ray diffraction (XRD)      Raman spectrum      luminescence  
Received:  31 July 2020      Revised:  23 November 2020      Accepted manuscript online:  01 December 2020
PACS:  65.40.De (Thermal expansion; thermomechanical effects)  
  81.05.Je (Ceramics and refractories (including borides, carbides, hydrides, nitrides, oxides, and silicides))  
  61.50.-f (Structure of bulk crystals)  
  78.30.-j (Infrared and Raman spectra)  
Fund: Project supported by the National Natural Science Foundation of China (Grant Nos. 11874328, U1731121, and 41401384) and the Shandong Province Higher Educational Science and Technology Program, China (Grant No. J17KB127).
Corresponding Authors:  Corresponding author. E-mail:   

Cite this article: 

Jun-Ping Wang(王俊平), Qing-Dong Chen(陈庆东), Li-Gang Chen(陈立刚), Yan-Jun Ji(纪延俊), You-Wen Liu(刘友文), and Er-Jun Liang(梁二军) Low thermal expansion and broad band photoluminescence of Zr0.1Al1.9Mo2.9V0.1O12 2021 Chin. Phys. B 30 036501

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