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Chin. Phys. B, 2020, Vol. 29(2): 026104    DOI: 10.1088/1674-1056/ab65b9
TOPICAL REVIEW—Overcoming doping bottleneck in widegap semiconductors Prev   Next  

Growth and doping of bulk GaN by hydride vapor phase epitaxy

Yu-Min Zhang(张育民)1,2, Jian-Feng Wang(王建峰)1,2, De-Min Cai(蔡德敏)2, Guo-Qiang Ren(任国强)1, Yu Xu(徐俞)1,2, Ming-Yue Wang(王明月)1,2, Xiao-Jian Hu(胡晓剑)1,2, Ke Xu(徐科)1,2
1 Suzhou Institute of Nano-tech and Nano-bionics, Chinese Academy of Sciences, Suzhou 215123, China;
2 Suzhou Nanowin Science and Technology Co., Ltd., Suzhou 215123, China
Abstract  Doping is essential in the growth of bulk GaN substrates, which could help control the electrical properties to meet the requirements of various types of GaN-based devices. The progresses in the growth of undoped, Si-doped, Ge-doped, Fe-doped, and highly pure GaN by hydride vapor phase epitaxy (HVPE) are reviewed in this article. The growth technology and precursors of each type of doping are introduced. Besides, the influence of doping on the optical and electrical properties of GaN are presented in detail. Furthermore, the problems caused by doping, as well as the methods to solve them are also discussed. At last, highly pure GaN is briefly introduced, which points out a new way to realize high-purity semi-insulating (HPSI) GaN.
Keywords:  GaN      hydride vapor phase epitaxy (HVPE)      doping  
Received:  31 October 2019      Revised:  14 December 2019      Accepted manuscript online: 
PACS:  61.72.uj (III-V and II-VI semiconductors)  
  81.05.Ea (III-V semiconductors)  
  81.10.Bk (Growth from vapor)  
  61.72.-y (Defects and impurities in crystals; microstructure)  
Fund: Project supported by the National Key Research and Development Program of China (Grant Nos. 2017YFB0404100 and 2016YFA0201101), the National Natural Science Foundation of China (Grant Nos. 61574164, 61704187, and 61604170), the Key Research Program of the Frontier Science of the Chinese Academy of Sciences (Grant No. QYZDB-SSW-SLH042), the State Key Program of the National Natural Science Foundation of China (Grant Nos. 61734008 and 11435010), and the National Key Scientific Instrument and Equipment Development Project, China (Grant No. 11327804).
Corresponding Authors:  Jian-Feng Wang, Ke Xu     E-mail:  jfwang2006@sinano.ac.cn;kxu2006@sinano.ac.cn

Cite this article: 

Yu-Min Zhang(张育民), Jian-Feng Wang(王建峰), De-Min Cai(蔡德敏), Guo-Qiang Ren(任国强), Yu Xu(徐俞), Ming-Yue Wang(王明月), Xiao-Jian Hu(胡晓剑), Ke Xu(徐科) Growth and doping of bulk GaN by hydride vapor phase epitaxy 2020 Chin. Phys. B 29 026104

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