Near-zero thermal expansion of In2(1-x)(HfMg)xMo3O12 with tailored phase transition

doi:10.1088/1674-1056/25/8/086501

Abstract Solid solutions of In_2(1-x)(HfMg)_xMo₃O₁₂ are synthesized by solid state reaction with the aim to reduce the phase transition temperature of In₂Mo₃O₁₂ and improve its thermal expansion property. The effects of (HfMg)⁶⁺ incorporation on the phase transition and thermal expansion are investigated. It is shown that the monoclinic-to-orthorhombic phase transition temperature obviously decreases and the coefficient of thermal expansion (CTE) of the orthorhombic becomes less negative and approaches to zero with increasing the content of (HfMg)⁶⁺. A near zero thermal expansion covering the case at room temperature (RT) is achieved for the solid solutions with x≥0.85, implying potential applications of this material in many fields.

Keywords: phase transition thermal expansion thermal analysis Raman spectrum

Received: 17 March 2016
Revised: 11 April 2016
Accepted manuscript online:

PACS:	61.50.Ks	(Crystallographic aspects of phase transformations; pressure effects)
	65.40.De	(Thermal expansion; thermomechanical effects)
	64.60.-i	(General studies of phase transitions)
	78.30.-j	(Infrared and Raman spectra)

Fund: Project supported by the National Natural Science Foundation of China (Grant Nos. 11574276, 51302249, and 51503185) and the Doctoral Fund of the Ministry of Education of China (Grant No. 20114101110003).

Corresponding Authors: Er-Jun Liang
E-mail: ejliang@zzu.edu.cn

Cite this article:

Yong-Guang Cheng(程永光), Yan-Chao Mao(毛彦超), Xain-Sheng Liu(刘献省), Bao-He Yuan(袁保合), Ming-Ju Chao(晁明举), Er-Jun Liang(梁二军) Near-zero thermal expansion of In_2(1-x)(HfMg)_xMo₃O₁₂ with tailored phase transition 2016 Chin. Phys. B 25 086501

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Near-zero thermal expansion of In2(1-x)(HfMg)xMo3O12 with tailored phase transition

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Near-zero thermal expansion of In_2(1-x)(HfMg)_xMo₃O₁₂ with tailored phase transition