Please wait a minute...
Chin. Phys. B, 2014, Vol. 23(11): 118202    DOI: 10.1088/1674-1056/23/11/118202
RAPID COMMUNICATION Prev   Next  

Novel copper redox-based cathode materials for room-temperature sodium-ion batteries

Xu Shu-Yin, Wu Xiao-Yan, Li Yun-Ming, Hu Yong-Sheng, Chen Li-Quan
Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China
Abstract  

Layered oxides of P2-type Na0.68Cu0.34Mn0.66O2, P2-type Na0.68Cu0.34Mn0.50Ti0.16O2, and O'3-type NaCu0.67Sb0.33O2 were synthesized and evaluated as cathode materials for room-temperature sodium-ion batteries. The first two materials can deliver a capacity of around 70 mAh/g. The Cu2+ is oxidized to Cu3+ during charging, and the Cu3+ goes back to Cu2+ upon discharging. This is the first demonstration of the highly reversible change of the redox couple of Cu2+/Cu3+ with high storage potential in secondary batteries.

Keywords:  energy storage      sodium-ion battery      cathode      copper redox  
Received:  22 September 2014      Revised:  29 September 2014      Accepted manuscript online: 
PACS:  82.45.Yz (Nanostructured materials in electrochemistry)  
  82.47.Aa (Lithium-ion batteries)  
  82.47.Cb (Lead-acid, nickel-metal hydride and other batteries)  
  84.60.-h (Direct energy conversion and storage)  
Corresponding Authors:  Hu Yong-Sheng     E-mail:  yshu@aphy.iphy.ac.cn

Cite this article: 

Xu Shu-Yin, Wu Xiao-Yan, Li Yun-Ming, Hu Yong-Sheng, Chen Li-Quan Novel copper redox-based cathode materials for room-temperature sodium-ion batteries 2014 Chin. Phys. B 23 118202

[1] Armand M and Tarascon J M 2008 Nature 451 652
[2] Tarascon J M 2010 Nat. Chem. 2 510
[3] Tarascon J M and Armand M 2001 Nature 414 359
[4] Pan H, Hu Y S and Chen L 2013 Energy Environ. Sci. 6 2338
[5] Slater M D, Kim D, Lee E and Johnson C S 2013 Adv. Funct. Mater. 23 947
[6] Kim S W, Seo D H, Ma X, Ceder G and Kang K 2012 Adv. Energy Mater. 2 710
[7] Palomares V, Serras P, Villaluenga I, Hueso K B, Carretero-González J and Rojo T 2012 Energy Environ. Sci. 5 5884
[8] Delmas C, Braconnier J J, Fouassier C and Hagenmuller P 1981 Solid State Ion. 3-4 165
[9] Mendiboure A, Delmas C and Hagenmuller P 1985 J. Solid State Chem. 57 323
[10] Doeff M M, Peng M Y, Ma Y and Jonghe L C D 1994 J. Electrochem. Soc. 141 L145
[11] Stevensa D A and Dahn J R 2000 J. Electrochem. Soc. 147 1271
[12] Zhao L, Zhao J, Hu Y S, Li H, Zhou Z, Armand M and Chen L 2012 Adv. Energy Mater. 2 962
[13] Zhao L, Pan H L, Hu Y S, Li H and Chen L Q 2012 Chin. Phys. B 21 028201
[14] Sun Y, Zhao L, Pan H, Lu X, Gu L, Hu Y S, Li H, Armand M, Ikuhara Y, Chen L and Huang X 2013 Nat. Commun. 4 1870
[15] Yu X, Pan H, Wan W, Ma C, Bai J, Meng Q, Ehrlich S N, Hu Y S and Yang X Q 2013 Nano Lett. 13 4721
[16] Yabuuchi N, Yano M, Yoshida H, Kuze S and Komaba S 2013 J. Electrochem. Soc. 160 A3131
[17] Pan H, Lu X, Yu X, Hu Y S, Li H, Yang X Q and Chen L 2013 Adv. Energy Mater. 3 1186
[18] Jian Z, Zhao L, Pan H, Hu Y S, Li H, Chen W and Chen L 2012 Electrochem. Commun. 14 86
[19] Jian Z, Han W, Lu X, Yang H, Hu Y S, Zhou J, Zhou Z, Li J, Chen W, Chen D and Chen L 2013 Adv. Energy Mater. 3 156
[20] Wang Y, Yu X Q, Xu S Y, Bai J, Xiao R J, Hu Y S, Li H, Yang X Q, Chen L Q and Huang X J 2013 Nat. Commun. 4 2365
[21] Barpanda P, Oyama G, Nishimura S, Chung S C and Yamada A 2014 Nat. Commun. 5 4358
[22] Okada S, Takahashi Y, Kiyabu T, Doi T, Yamaki J and Nishida T 2006 210th ECS Meeting Abstracts, MA2006-02, 201
[23] Yabuuchi N, Kajiyama M, Iwatate J, Nishikawa H, Hitomi S, Okuyama R, Usui R, Yamada Y and Komaba S 2012 Nat. Mater. 11
[24] Sathiya M, Hemalatha K, Ramesha K, Tarascon J M and Prakash A S 2012 Chem. Mater. 24 1846
[25] Braconnier J J, Delmas C and Hagenmuller P 1982 Mater. Res. Bull. 17 993
[26] Kim D, Lee E, Slater M, Lu W, Rood S and Johnson C S 2012 Electrochem. Commun. 18 66
[27] Xu J, Lee D H, Clément R J, Yu X, Leskes M, Andrew, Pell J, Pintacuda G, Yang X Q, Grey C P and Meng Y S 2014 Chem. Mater. 26 1260
[28] Yabuuchi N, Hara R, Kajiyama M, Kubota K, Ishigaki T, Hoshikawa A and Komaba S 2014 Adv. Energy Mater. na
[29] Kim D, Kang S H, Slater M, Rood S, Vaughey J T, Karan N, Balasubramanian M and Johnson C S 2011 Adv. Energy Mater. 1 333
[30] Lu Z and Dahn J R 2001 J. Electrochem. Soc. 148 A1225
[31] Delmas C, Fouassier C and Hagenmuller P 1980 Physica B 99 81
[32] Wang X, Tamaru M, Okubo M and Yamada A 2013 J. Phys. Chem. C 117 15545
[33] Smirnova O A, Nalbandyan V B, Petrenko A A and Avdeev M 2005 J. Solid State Chem. 178 1165
[1] Two-dimensional MnN utilized as high-capacity anode for Li-ion batteries
Junping Hu(胡军平), Zhangyin Wang(王章寅), Genrui Zhang(张根瑞), Yu Liu(刘宇), Ning Liu(刘宁), Wei Li(李未), Jianwen Li(李健文), Chuying Ouyang(欧阳楚英), and Shengyuan A. Yang(杨声远). Chin. Phys. B, 2021, 30(4): 046302.
[2] Suppressing transition metal dissolution and deposition in lithium-ion batteries using oxide solid electrolyte coated polymer separator
Zhao Yan(闫昭), Hongyi Pan(潘弘毅), Junyang Wang(汪君洋), Rusong Chen(陈汝颂), Fei Luo(罗飞), Xiqian Yu(禹习谦), Hong Li(李泓). Chin. Phys. B, 2020, 29(8): 088201.
[3] Revealing the inhomogeneous surface chemistry on the spherical layered oxide polycrystalline cathode particles
Zhi-Sen Jiang(蒋之森), Shao-Feng Li(李少锋), Zheng-Rui Xu(许正瑞), Dennis Nordlund, Hendrik Ohldag, Piero Pianetta, Jun-Sik Lee, Feng Lin(林锋), Yi-Jin Liu(刘宜晋). Chin. Phys. B, 2020, 29(2): 026103.
[4] Energy storage performances regulated by BiMnO3 proportion in limited solid solution films
Fei Guo(郭飞), Zhifeng Shi(史智锋), Yaping Liu(刘亚平), and Shifeng Zhao(赵世峰). Chin. Phys. B, 2020, 29(11): 116801.
[5] Plasma simulation to analyze velocity distribution characteristics of pseudospark-sourced electron beam
Hai-Long Li(李海龙)†, Chen-Fei Hu(胡陈飞), Che Xu(徐彻), Yong Yin(殷勇), Bin Wang(王彬), Lin Meng(蒙林), and Mao-Yan Wang(王茂琰). Chin. Phys. B, 2020, 29(10): 105101.
[6] Fluctuation of arc plasma in arc plasma torch with multiple cathodes
Zelong Zhang(张泽龙), Cheng Wang(王城), Qiang Sun(孙强), Weidong Xia(夏维东). Chin. Phys. B, 2019, 28(9): 095201.
[7] Improved electrochemical performance of Li(Ni0.6Co0.2Mn0.2)O2 at high charging cut-off voltage with Li1.4Al0.4Ti1.6(PO4)3 surface coating
Yi Wang(王怡), Bo-Nan Liu(刘柏男), Ge Zhou(周格), Kai-Hui Nie(聂凯会), Jie-Nan Zhang(张杰男), Xi-Qian Yu(禹习谦), Hong Li(李泓). Chin. Phys. B, 2019, 28(6): 068202.
[8] Improved electrochemical performances of high voltage LiCoO2 with tungsten doping
Jie-Nan Zhang(张杰男), Qing-Hao Li(李庆浩), Quan Li(李泉), Xi-Qian Yu(禹习谦), Hong Li(李泓). Chin. Phys. B, 2018, 27(8): 088202.
[9] Free-standing, curled and partially reduced graphene oxide network as sulfur host for high-performance lithium-sulfur batteries
Hui-Liang Chen(陈辉亮), Zhuo-Jian Xiao(肖卓建), Nan Zhang(张楠), Shi-Qi Xiao(肖仕奇), Xiao-Gang Xia(夏晓刚), Wei Xi(席薇), Yan-Chun Wang(王艳春), Wei-Ya Zhou(周维亚), Si-Shen Xie(解思深). Chin. Phys. B, 2018, 27(6): 068101.
[10] Current loss of magnetically insulated coaxial diode with cathode negative ion
Dan-Ni Zhu(朱丹妮), Jun Zhang(张军), Hui-Huang Zhong(钟辉煌), Jing-Ming Gao(高景明), Zhen Bai(白珍). Chin. Phys. B, 2018, 27(2): 020501.
[11] A low-outgassing-rate carbon fiber array cathode
An-Kun Li(李安昆), Yu-Wei Fan(樊玉伟), Bao-Liang Qian(钱宝良), Zi-Cheng Zhang(张自成), Tao Xun(荀涛). Chin. Phys. B, 2018, 27(2): 028401.
[12] Effects of Al component content on optoelectronic properties of AlxGa1-xN
Yan-Jun Ji(纪延俊), Jun-Ping Wang(王俊平), You-Wen Liu(刘友文). Chin. Phys. B, 2018, 27(10): 106102.
[13] A theoretical and experimental evaluation of III-nitride solar-blind UV photocathode
Bin Ren(任彬), Hui Guo(郭晖), Feng Shi(石峰), Hong-Chang Cheng(程宏昌), Hui Liu(刘晖), Jian Liu(刘健), Zhi-Hui Shen(申志辉), Yan-Li Shi(史衍丽), Pei Liu(刘培). Chin. Phys. B, 2017, 26(8): 088504.
[14] Production of a large area diffuse arc plasma with multiple cathode
Cheng Wang(王城), Hai-Chao Cui(崔海超), Wan-Wan Li(李皖皖), Meng-Ran Liao(廖梦然), Wei-Luo Xia(夏维珞), Wei-Dong Xia(夏维东). Chin. Phys. B, 2017, 26(2): 025202.
[15] Enhanced energy storage behaviors in free-standing antiferroelectric Pb(Zr0.95Ti0.05)O3 thin membranes
Zheng-Hu Zuo(左正笏), Qing-Feng Zhan(詹清峰), Bin Chen(陈斌), Hua-Li Yang(杨华礼), Yi-Wei Liu(刘宜伟), Lu-Ping Liu(刘鲁萍), Ya-Li Xie(谢亚丽), Run-Wei Li(李润伟). Chin. Phys. B, 2016, 25(8): 087702.
No Suggested Reading articles found!