Liquid-phase and solid-phase microwave irradiations for reduction of graphite oxide

doi:10.1088/1674-1056/23/12/128101

›› 2014, Vol. 23 ›› Issue (12): 128101-128101.doi: 10.1088/1674-1056/23/12/128101

• INTERDISCIPLINARY PHYSICS AND RELATED AREAS OF SCIENCE AND TECHNOLOGY • 上一篇下一篇

Liquid-phase and solid-phase microwave irradiations for reduction of graphite oxide

赵娜^a, 文宸宇^a, 张卫^a, 吴东平^a, 张志滨^b, 张世理^b

a State Key Laboratory of ASIC and System, Fudan University, Shanghai 200433, China;
b Solid-State Electronics, The Ångström Laboratory, Uppsala University, P. O. Box 534, 75121 Uppsala, Sweden

收稿日期:2014-02-24 修回日期:2014-06-21 出版日期:2014-12-15 发布日期:2014-12-15
基金资助:
Project supported by the National Natural Science Foundation of China (Grant No. 61176090) and the National Science and Technology Project 02, China (Grant No. 2013ZX02303-004).

Liquid-phase and solid-phase microwave irradiations for reduction of graphite oxide

Zhao Na (赵娜)^a, Wen Chen-Yu (文宸宇)^a, Zhang David Wei (张卫)^a, Wu Dong-Ping (吴东平)^a, Zhang Zhi-Bin (张志滨)^b, Zhang Shi-Li (张世理)^b

a State Key Laboratory of ASIC and System, Fudan University, Shanghai 200433, China;
b Solid-State Electronics, The Ångström Laboratory, Uppsala University, P. O. Box 534, 75121 Uppsala, Sweden

Received:2014-02-24 Revised:2014-06-21 Online:2014-12-15 Published:2014-12-15
Contact: Wu Dong-Ping E-mail:dongpingwu@fudan.edu.cn
Supported by:
Project supported by the National Natural Science Foundation of China (Grant No. 61176090) and the National Science and Technology Project 02, China (Grant No. 2013ZX02303-004).

摘要/Abstract

摘要： In this paper, two microwave irradiation methods: (i) liquid-phase microwave irradiation (MWI) reduction of graphite oxide suspension dissolved in de-ionized water and N, N-dimethylformamide, respectively, and (ii) solid-phase MWI reduction of graphite oxide powder have been successfully carried out to reduce graphite oxide. The reduced graphene oxide products are thoroughly characterized by scanning electron microscopy, atomic force microscopy, X-ray photoelectron spectroscopy, Fourier transform infrared spectral analysis, Raman spectroscopy, UV-Vis absorption spectral analysis, and four-point probe conductivity measurements. The results show that both methods can efficiently remove the oxygen-containing functional groups attached to the graphite layers, though the solid-phase MWI reduction method can obtain far more efficiently a higher quality-reduced graphene oxide with fewer defects. The I(D)/I(G) ratio of the solid-phase MWI sample is as low as 0.46, which is only half of that of the liquid-phase MWI samples. The electrical conductivity of the reduced graphene oxide by the solid method reaches 747.9 S/m, which is about 25 times higher than that made by the liquid-phase method.

关键词: microwave irradiation, solid-phase, liquid-phase, reduced graphene oxide

Abstract: In this paper, two microwave irradiation methods: (i) liquid-phase microwave irradiation (MWI) reduction of graphite oxide suspension dissolved in de-ionized water and N, N-dimethylformamide, respectively, and (ii) solid-phase MWI reduction of graphite oxide powder have been successfully carried out to reduce graphite oxide. The reduced graphene oxide products are thoroughly characterized by scanning electron microscopy, atomic force microscopy, X-ray photoelectron spectroscopy, Fourier transform infrared spectral analysis, Raman spectroscopy, UV-Vis absorption spectral analysis, and four-point probe conductivity measurements. The results show that both methods can efficiently remove the oxygen-containing functional groups attached to the graphite layers, though the solid-phase MWI reduction method can obtain far more efficiently a higher quality-reduced graphene oxide with fewer defects. The I(D)/I(G) ratio of the solid-phase MWI sample is as low as 0.46, which is only half of that of the liquid-phase MWI samples. The electrical conductivity of the reduced graphene oxide by the solid method reaches 747.9 S/m, which is about 25 times higher than that made by the liquid-phase method.

Key words: microwave irradiation, solid-phase, liquid-phase, reduced graphene oxide

中图分类号: (Specific materials: fabrication, treatment, testing, and analysis)

81.05.-t

81.05.U- (Carbon/carbon-based materials) 81.05.ue (Graphene)

赵娜, 文宸宇, 张卫, 吴东平, 张志滨, 张世理. Liquid-phase and solid-phase microwave irradiations for reduction of graphite oxide[J]. , 2014, 23(12): 128101-128101.

Zhao Na (赵娜), Wen Chen-Yu (文宸宇), Zhang David Wei (张卫), Wu Dong-Ping (吴东平), Zhang Zhi-Bin (张志滨), Zhang Shi-Li (张世理). Liquid-phase and solid-phase microwave irradiations for reduction of graphite oxide[J]. Chin. Phys. B, 2014, 23(12): 128101-128101.

参考文献 0


[1]	Gómez-Navarro C, Weitz R T, Bittner A M, Scolari M, Mews A, Burghard M and Kern K 2007 Nano Lett. 7 3499 doi: 10.1021/nl072090c

[2]	Gilje S, Han S, Wang M, Wang K L and Kaner R B 2007 Nano Lett. 7 3394 doi: 10.1021/nl0717715

[3]	Geim A K and Novoselov K S 2007 Nat. Mater. 6 183 doi: 10.1038/nmat1849

[4]	Liang X, Fu Z and Chou S Y 2007 Nano Lett. 7 3840 doi: 10.1021/nl072566s

[5]	Novoselov K S, Geim A K, Morozov S V, Jiang D, Zhang Y, Dubonos S V, Grigorieva I V and Firsov A A 2004 Science 306 666 doi: 10.1126/science.1102896

[6]	Watcharotone S, Dikin D A, Stankovich S, Piner R, Jung I, Dommett G H B, Evmenenko G, Wu S E, Chen S F, Liu C P, Nguyen S T and Ruoff R S 2007 Nano Lett. 7 1888 doi: 10.1021/nl070477+

[7]	Eda G, Fanchini G and Chhowalla M 2008 Nat. Nanotechnol. 3 270 doi: 10.1038/nnano.2008.83

[8]	Blake P, Brimicombe P D, Nair R R, Booth T J, Jiang D, Schedin F, Ponomarenko L A, Morozov S V, Gleeson H F, Hill E W, Geim A K and Novoselov K S 2008 Nano Lett. 8 1704 doi: 10.1021/nl080649i

[9]	Hassan H M A, Abdelsayed V, Khder A E R S, AbouZeid K M, Terner J, El-Shall M S, Al-Resayes S I and El-Azhary A A 2009 J. Mater. Chem. 19 3832 doi: 10.1039/b906253j

[10]	Ambrosi A and Pumera M 2013 J. Phys. Chem. C 117 2053

[11]	Li X S, Cai W W, An J H, Kim S Y, Nah J H, Yang D X, Piner R, Velamakanni A, Jung I, Tutuc E, Banerjee K S, Colombo L and Ruoff R S 2009 Science 324 1312 doi: 10.1126/science.1171245

[12]	Ren W C, Gao L B, Ma L P and Cheng H M 2011 New Carbon Mater. 26 71

[13]	Kim K S, Zhao Y, Jang H, Lee S Y, Kim J M, Kim K S, Ahn J H, Kim P, Choi J Y and Hong B H 2009 Nature 457 706 doi: 10.1038/nature07719

[14]	Fernández-Merino M J, Guardia L, Paredes J I, Villar-Rodil S, Solís-Fernández P, Martínez-Alonso A and Tascón J M D 2010 J. Phys. Chem. C 114 6426

[15]	Wang D C, Zhang Y M, Zhang Y M, Lei T M, Guo H, Wang Y H, Tang X Y and Wang H 2011 Chin. Phys. B 20 128101

[16]	Wang D C, Zhang Y M, Zhang Y M, Lei T M, Guo H, Wang Y H, Tang X Y and Wang H 2012 Chin. Phys. B 21 038102

[17]	Simpson C D, Mattersteig G, Martin K, Gherghel L, Bauer R E, Räder H J and Müllen K 2004 J. Am. Chem. Soc. 126 3139 doi: 10.1021/ja036732j

[18]	Zhu Y W, Murali S, Stoller M D, Velamakanni A, Piner R D and Ruoff R S 2010 Carbon 48 2118 doi: 10.1016/j.carbon.2010.02.001

[19]	Paton K R and Windle A H 2008 Carbon 46 1935 doi: 10.1016/j.carbon.2008.08.001

[20]	Imholt T J, Dyke C A, Hasslacher B, Perez J M, Price D W, Roberts J A, Scott J B, Wadhawan A, Ye Z and Tour J M 2003 Chem. Mater. 15 3969 doi: 10.1021/cm034530g

[21]	Park S H, Bak S M, Kim K H, Jegal J P, Lee S I, Lee J and Kim K B 2011 J. Mater. Chem. 21 680 doi: 10.1039/c0jm01007c

[22]	Zhu C Z, Guo S J, Fang Y X and Dong S J 2010 ACS Nano 4 2429 doi: 10.1021/nn1002387

[23]	Negra F D, Meneghetti M and Menna E 2003 Fullerenes, Nanotubes and Carbon Nanostructures 11 25 doi: 10.1081/FST-120018668

[24]	Wang B G, Wang X B, Lou W J and Hao J C 2012 New J. Chem. 36 1684 doi: 10.1039/c2nj40204a

[25]	Gao W, Alemany L B, Ci L and Ajayan P M 2009 Nat. Chem. 1 403 doi: 10.1038/nchem.281

[26]	Chen W F and Yan L F 2010 Nanoscale 2 559 doi: 10.1039/b9nr00191c

[27]	Liao K H, Mittal A, Bose S, Leighton C, Mkhoyan K A and Macosko C W 2011 ACS Nano 5 1253 doi: 10.1021/nn1028967

[28]	Fan X B, Peng W C, Li Y, Li X Y, Wang S L, Zhang G L and Zhang F B 2008 Adv. Mater. 20 4490 doi: 10.1002/adma.200801306

[29]	Glover A J, Cai M, Overdeep K R, Kranbuehl D E and Schniepp H C 2011 Macromolecules 44 9821 doi: 10.1021/ma2008783

[30]	Zangmeister C D 2010 Chem. Mater. 22 5625 doi: 10.1021/cm102005m

[31]	Shin H J, Kim K K, Benayad A, Yoon S M, Park H K, Jung I S, Jin M H, Jeong H K, Kim J M, Choi J Y and Lee Y H 2009 Adv. Func. Mater. 19 1987 doi: 10.1002/adfm.200900167

[32]	Williams G, Seger B and Kamat P V 2008 ACS Nano 2 1487 doi: 10.1021/nn800251f

[33]	Lei Z B, Lu L and Zhao X S 2012 Energy & Environ. Sci. 5 6391 doi: y

[34]	López V, Sundaram R S, Gómez-Navarro C, Olea D, Burghard M, Gómez-Herrero J, Zamora F and Kern K 2009 Adv. Mater. 21 4683

[35]	Vivek P, Rajender S V 2010 Aqueous Microwave Assisted Chemistry Synthesis and Catalysis (Cambridge: Royal Society of Chemistry) pp. 4-8

Liquid-phase and solid-phase microwave irradiations for reduction of graphite oxide

Liquid-phase and solid-phase microwave irradiations for reduction of graphite oxide

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