Ionic conductivity study on electron beam irradiated polyacrylonitrile–polyethylene oxide gel

doi:10.1088/1674-1056/20/7/078104

中国物理B ›› 2011, Vol. 20 ›› Issue (7): 78104-078104.doi: 10.1088/1674-1056/20/7/078104

Ionic conductivity study on electron beam irradiated polyacrylonitrile–polyethylene oxide gel

马艺准, 庞立龙, 朱亚滨, 王志光, 申铁龙

Institute of Modern Physics, Lanzhou 730000, China

收稿日期:2010-12-14 修回日期:2011-01-14 出版日期:2011-07-15 发布日期:2011-07-15

Ionic conductivity study on electron beam irradiated polyacrylonitrile–polyethylene oxide gel

Ma Yi-Zhun (马艺准)^a)b),Pang Li-Long(庞立龙)^a)b),Zhu Ya-Bin(朱亚滨)^a)b), Wang Zhi-Guang(王志光)^a)^†, and Shen Tie-Long(申铁龙)^a)b)

^aInstitute of Modern Physics, Lanzhou 730000, China; ^b Graduate University of Chinese Academy of Sciences, Beijing 100490, China

Received:2010-12-14 Revised:2011-01-14 Online:2011-07-15 Published:2011-07-15

摘要/Abstract

摘要： Different mass percent polyacrylonitrile (PAN)—polyethylene oxide (PEO) gels were prepared and irradiated by an electron beam (EB) with energy of 1.0 MeV to the dose ranging from 13 kGy to 260 kGy. The gels were analysed by using Fourier transform infrared spectrum, gel fraction and ionic conductivity (IC) measurement. The results show that the gel is crosslinked by EB irradiation, the crosslinking degree rises with the increasing EB irradiation dose (ID) and the mass percents of both PAN and PEO contribute a lot to the crosslinking; in addition, EB irradiation can promote the IC of PAN—PEO gels. There exists an optimum irradiation dose, at which the IC can increase dramatically. The IC changes of the PAN—PEO gels along with ID are divided into three regions: IC rapidly increasing region, IC decreasing region and IC balanced region. The cause of the change can be ascribed to two aspects, gel capturing electron degree and crosslinking degree. By comparing the IC—ID curves of different mass percents of PAN and PEO in gel, we found that PAN plays a more important role for gel IC promotion than PEO, since addition of PAN in gel causes the IC—ID curve sharper, while addition of PEO in gel causes the curve milder.

关键词: polyacrylonitrile, polyethylene oxide, electron beam irradiation, ionic conductivity

Abstract: Different mass percent polyacrylonitrile (PAN)–polyethylene oxide (PEO) gels were prepared and irradiated by an electron beam (EB) with energy of 1.0 MeV to the dose ranging from 13 kGy to 260 kGy. The gels were analysed by using Fourier transform infrared spectrum, gel fraction and ionic conductivity (IC) measurement. The results show that the gel is crosslinked by EB irradiation, the crosslinking degree rises with the increasing EB irradiation dose (ID) and the mass percents of both PAN and PEO contribute a lot to the crosslinking; in addition, EB irradiation can promote the IC of PAN–PEO gels. There exists an optimum irradiation dose, at which the IC can increase dramatically. The IC changes of the PAN–PEO gels along with ID are divided into three regions: IC rapidly increasing region, IC decreasing region and IC balanced region. The cause of the change can be ascribed to two aspects, gel capturing electron degree and crosslinking degree. By comparing the IC–ID curves of different mass percents of PAN and PEO in gel, we found that PAN plays a more important role for gel IC promotion than PEO, since addition of PAN in gel causes the IC–ID curve sharper, while addition of PEO in gel causes the curve milder.

Key words: polyacrylonitrile, polyethylene oxide, electron beam irradiation, ionic conductivity

中图分类号: (Ion and electron beam-assisted deposition; ion plating)

81.15.Jj

82.70.Gg (Gels and sols)

马艺准, 庞立龙, 朱亚滨, 王志光, 申铁龙. Ionic conductivity study on electron beam irradiated polyacrylonitrile–polyethylene oxide gel[J]. 中国物理B, 2011, 20(7): 78104-078104.

Ma Yi-Zhun (马艺准), Pang Li-Long(庞立龙), Zhu Ya-Bin(朱亚滨), Wang Zhi-Guang(王志光), and Shen Tie-Long(申铁龙) . Ionic conductivity study on electron beam irradiated polyacrylonitrile–polyethylene oxide gel[J]. Chin. Phys. B, 2011, 20(7): 78104-078104.

参考文献 32

[1]	Choi B K, Kim Y W and Shin H K 2000 Electrochim. Acta 45 1371
[2]	Rajendran S, Mahalingam T and Kannan R 2000 Solid State Ionics 130 143
[3]	Yuan F, Chen H Z, Yang H Y, Li H Y and Wang M 2005 Mater. Chem. Phys. 89 390
[4]	Uchiyama R, Kusagawa K, Hanai K, Imanishi N, Hirano A and Takeda Y 2009 Solid State Ionics 180 205
[5]	Akhtar M S, Choi D J, Lee S K and Yang O B 2010 Curr. Appl. Phys. 10 S161
[6]	Oliveira V M, Ortiz A V, Mastro N L and Moura E A B 2009 Radiat. Phys. Chem. 78 553
[7]	Mishra J K, Chang Y W, Lee B C and Ryu S H 2008 Radiat. Phys. Chem. 77 675
[8]	Vijayabaskar V, Stephan M, Kalaivani S, Volke S, Heinrich G, Dorschner H, Bhowmick A K and Wagenknecht U 2008 Radiat. Phys. Chem. 77 511
[9]	Cerrada M L, Benavente R, Fernandez-Garcia M, Perez E, Campos J M and Ribeiro M R 2009 Polym. J. 50 1095
[10]	Sheikh N, Jalili L and Anvari F 2010 Radiat. Phys. Chem. 79 735
[11]	Zagorski Z P 2004 Radiat. Phys. Chem. 71 261
[12]	Hwang I T, Jung C H, Kuk I S, Choi J H and Nho Y C 2010 Nucl. Instrum. Methods in Phys. Res., Sect. B bf 268 3368
[13]	Perraud S, Vallat M F, David M O and Kuczynski J 2010 Polym. Degrad. Stab. 95 1495
[14]	Ying S K 1964 J. Dalian Univ. Technol. 3 69 (in Chinese)
[15]	Xiong B T, Zhou B X, Bai J, Zheng Q, Liu Y B, Cai W M and Cai J 2008 Chin. Phys. B 17 3713
[16]	Guo L, Liang L Y, Chen C, Wang M T, Kong M G and Wang K J 2007 Acta Phys. Sin. 56 4270 (in Chinese)
[17]	Liu W Q, Kou D X, Hu L H, Huang Y and Jiang N Q 2010 Acta Phys. Sin. 59 5141 (in Chinese)
[18]	Liang L Y, Dai S Y, Hu L H, Dai J and Liu W Q 2009 Acta Phys. Sin. 58 1338 (in Chinese)
[19]	Kou D X, Liu W Q, Hu L H, Huang Y, Dai S Y and Jiang N Q 2010 Acta Phys. Sin. 59 5857 (in Chinese)
[20]	Liang L Y, Dai S Y, Fang X Q and Hu L H 2008 Acta Phys. Sin. 57 1956 (in Chinese)
[21]	Zagórski Z P 2004 Radiat. Phys. Chem. 71 263
[22]	Sheikh N, Jalili L and Anvari F 2010 Radiat. Phys. Chem. 79 735
[23]	Linggawati A, Mohammad A W and Ghazali Z 2009 Eur. Polym. J. 45 2797
[24]	Yoshii F, Zhanshan Y, Isobe K, Shinozaki K and Makuuchi K 1999 Radiat. Phys. Chem. 55 133
[25]	Zhao L, Mitomo H, Zhai M L, Yoshii F, Nagasawa N and Kume T 2003 Carbohydr. Polym. 53 439
[26]	Gottlieb M H and Sollner K 1968 Biophys. J. bf 8 515
[27]	Johnson H D, Cooper W J, Mezyk S P and Bartels D M 2002 Radiat. Phys. Chem. 65 317
[28]	Zaikin Y A, Ismailova G A and Al-Sheikhly M 2007 it Radiat. Phys. Chem. 76 1404
[29]	Teruo M and Kyoichi S 1973 J. Appl. Phys. 44 5372
[30]	Yang H X, Huang M L, Wu J H, Lan Z, Hao S C and Lin J M 2008 Mater. Chem. Phys. 110 38
[31]	Wang Y M 2009 Sol. Energy Mater. Sol. Cells 93 1167
[32]	Li P J, Wu J H, Huang M L, Hao S C, Lan Z, Li Q H and Kang S J 2007 Electrochim. Acta 53 903

Ionic conductivity study on electron beam irradiated polyacrylonitrile–polyethylene oxide gel

Ionic conductivity study on electron beam irradiated polyacrylonitrile–polyethylene oxide gel

PDF (PC)

赞

可视化

摘要/Abstract

引用本文

使用本文

参考文献 32

相关文章 7

Metrics

本文评价

推荐阅读 0

[1]	封国宝, 刘璐, 崔万照, 王芳. Electron beam irradiation on novel coronavirus (COVID-19): A Monte-Carlo simulation[J]. 中国物理B, 2020, 29(4): 48703-048703.
[2]	赵兴宇, 王丽娜, 尹红梅, 周恒为, 黄以能. Measurement scheme to detect α relaxation time of glass-forming liquid[J]. 中国物理B, 2019, 28(8): 86601-086601.
[3]	徐航宇, 李泉, 潘弘毅, 邱纪亮, 曹文卓, 禹习谦, 李泓. Artificial solid electrolyte interphase based on polyacrylonitrile for homogenous and dendrite-free deposition of lithium metal[J]. 中国物理B, 2019, 28(7): 78202-078202.
[4]	陈军联, 左文彬, 柯贤文, Alexander B Tolstoguzov, 田灿鑫, Neena Devi, Ranjana Jha, Gennady N Panin, 付德君. Structure, conductivity, and ion emission properties of RbAg₄I₅ solid electrolyte film prepared by pulsed laser deposition[J]. 中国物理B, 2019, 28(6): 60705-060705.
[5]	王少飞, 陈立泉. Interfacial transport in lithium-ion conductors[J]. 中国物理B, 2016, 25(1): 18202-018202.
[6]	高健, 赵予生, 施思齐, 李泓. Lithium-ion transport in inorganic solid state electrolyte[J]. 中国物理B, 2016, 25(1): 18211-018211.
[7]	曹阳, 李忆秋, 郭向欣. Densification and lithium ion conductivity of garnet-type Li_7-xLa₃Zr_2-xTa_xO₁₂ (x=0.25) solid electrolytes[J]. 中国物理B, 2013, 22(7): 78201-078201.