Synthesis and performance of Zn-Ni-P thin films

doi:10.1088/1674-1056/24/3/036101

›› 2015, Vol. 24 ›› Issue (3): 36101-036101.doi: 10.1088/1674-1056/24/3/036101

• CONDENSED MATTER: STRUCTURAL, MECHANICAL, AND THERMAL PROPERTIES • 上一篇下一篇

Synthesis and performance of Zn-Ni-P thin films

V. Soare^a, M. Burada^a, I. Constantin^a, M. Ghita^a, V. Constantin^b, F. Miculescu^c, A. M. Popescu^b

a New Materials and Technologies Laboratory, National Research and Development Institute for Nonferrous and Rare Metals-IMNR, 102 Biruintei Blvd, Pantelimon, Ilfov-077145, Romania;
b Institute of Physical Chemistry “Ilie Murgulescu”, Laboratory of Molten Salts, 202 Splaiul Independentei, Bucharest-060021, Romania;
c University Polytehnica of Bucharest, Center of Biomaterials (BIOMAT), 313 Splaiul Independentei, Bucharest-060042, Romania

收稿日期:2014-07-04 修回日期:2014-10-07 出版日期:2015-03-05 发布日期:2015-03-05
基金资助:
Project support by the Partnership Romanian Research Program (PNCDI2), CORZIFILM Project nr.72-221/2008-2011 and “EU (ERDF) and Romanian Government” that allowed for acquisition of the research infrastructure under POS-CEEO 2.2.1 project INFRANANOCHEM-Nr.19/01.03.2009.

Synthesis and performance of Zn-Ni-P thin films

V. Soare^a, M. Burada^a, I. Constantin^a, M. Ghita^a, V. Constantin^b, F. Miculescu^c, A. M. Popescu^b

a New Materials and Technologies Laboratory, National Research and Development Institute for Nonferrous and Rare Metals-IMNR, 102 Biruintei Blvd, Pantelimon, Ilfov-077145, Romania;
b Institute of Physical Chemistry “Ilie Murgulescu”, Laboratory of Molten Salts, 202 Splaiul Independentei, Bucharest-060021, Romania;
c University Polytehnica of Bucharest, Center of Biomaterials (BIOMAT), 313 Splaiul Independentei, Bucharest-060042, Romania

Received:2014-07-04 Revised:2014-10-07 Online:2015-03-05 Published:2015-03-05
Contact: V. Constantin, A. M. Popescu E-mail:popescuamj@yahoo.com;virgilconstantin@yahoo.com
Supported by:
Project support by the Partnership Romanian Research Program (PNCDI2), CORZIFILM Project nr.72-221/2008-2011 and “EU (ERDF) and Romanian Government” that allowed for acquisition of the research infrastructure under POS-CEEO 2.2.1 project INFRANANOCHEM-Nr.19/01.03.2009.

摘要/Abstract

摘要： The electroplating of Zn-Ni-P thin film alloys from a sulfate bath containing phosphoric and phosphorous acid was investigated. The bath composition and the deposition parameters were optimized through Hull cell experiments, and the optimum experimental conditions were determined (pH = 2, temperature = 298-313 K, zinc sulfate concentration = 30 g· L^-1, EDTA concentration = 15 g· L^-1, and current density=1.0-2.0 A· dm^-2). The SEM analysis of the coating deposited from the optimum bath revealed fine-grained deposits of the alloy in the presence of EDTA. Optical microscopy analysis indicated an electrodeposited thin film with uniform thickness and good adhesion to the steel substrate. The good adherence of the coatings was also demonstrated by the scratch tests that were performed, with a maximum determined value of 25 N for the critical load. Corrosion resistance tests revealed good protection of the steel substrate by the obtained Zn-Ni-P coatings, with values up to 85.89% for samples with Ni contents higher than 76%. The surface analysis of the thin film samples before and after corrosion was performed by X-ray photoelectron spectroscopy (XPS).

关键词: thin film, corrosion, electrochemistry, surface

Abstract: The electroplating of Zn-Ni-P thin film alloys from a sulfate bath containing phosphoric and phosphorous acid was investigated. The bath composition and the deposition parameters were optimized through Hull cell experiments, and the optimum experimental conditions were determined (pH = 2, temperature = 298-313 K, zinc sulfate concentration = 30 g· L^-1, EDTA concentration = 15 g· L^-1, and current density=1.0-2.0 A· dm^-2). The SEM analysis of the coating deposited from the optimum bath revealed fine-grained deposits of the alloy in the presence of EDTA. Optical microscopy analysis indicated an electrodeposited thin film with uniform thickness and good adhesion to the steel substrate. The good adherence of the coatings was also demonstrated by the scratch tests that were performed, with a maximum determined value of 25 N for the critical load. Corrosion resistance tests revealed good protection of the steel substrate by the obtained Zn-Ni-P coatings, with values up to 85.89% for samples with Ni contents higher than 76%. The surface analysis of the thin film samples before and after corrosion was performed by X-ray photoelectron spectroscopy (XPS).

Key words: thin film, corrosion, electrochemistry, surface

中图分类号: (Alloys )

61.66.Dk

68.55.-a (Thin film structure and morphology) 81.65.Kn (Corrosion protection) 82.80.Pv (Electron spectroscopy (X-ray photoelectron (XPS), Auger electron spectroscopy (AES), etc.))

V. Soare, M. Burada, I. Constantin, M. Ghita, V. Constantin, F. Miculescu, A. M. Popescu. Synthesis and performance of Zn-Ni-P thin films[J]. , 2015, 24(3): 36101-036101.

V. Soare, M. Burada, I. Constantin, M. Ghita, V. Constantin, F. Miculescu, A. M. Popescu. Synthesis and performance of Zn-Ni-P thin films[J]. Chin. Phys. B, 2015, 24(3): 36101-036101.

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Synthesis and performance of Zn-Ni-P thin films

Synthesis and performance of Zn-Ni-P thin films

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