Fast high-resolution nuclear magnetic resonance spectroscopy through indirect zero-quantum coherence detection in inhomogeneous fields

doi:10.1088/1674-1056/23/6/063201

中国物理B ›› 2014, Vol. 23 ›› Issue (6): 63201-063201.doi: 10.1088/1674-1056/23/6/063201

• ATOMIC AND MOLECULAR PHYSICS • 上一篇下一篇

Fast high-resolution nuclear magnetic resonance spectroscopy through indirect zero-quantum coherence detection in inhomogeneous fields

柯汉平, 陈浩, 林雁勤, 韦芝良, 蔡淑惠, 张志勇, 陈忠

Department of Electronic Science, Fujian Provincial Key Laboratory of Plasma and Magnetic Resonance, Xiamen University, Xiamen 361005, China

收稿日期:2013-09-16 修回日期:2013-11-19 出版日期:2014-06-15 发布日期:2014-06-15
基金资助:
Project supported by the National Natural Science Foundation of China (Grant Nos. 11275161 and 11105114).

Fast high-resolution nuclear magnetic resonance spectroscopy through indirect zero-quantum coherence detection in inhomogeneous fields

Ke Han-Ping (柯汉平), Chen Hao (陈浩), Lin Yan-Qin (林雁勤), Wei Zhi-Liang (韦芝良), Cai Shu-Hui (蔡淑惠), Zhang Zhi-Yong (张志勇), Chen Zhong (陈忠)

Department of Electronic Science, Fujian Provincial Key Laboratory of Plasma and Magnetic Resonance, Xiamen University, Xiamen 361005, China

Received:2013-09-16 Revised:2013-11-19 Online:2014-06-15 Published:2014-06-15
Contact: Lin Yan-Qin, Cai Shu-Hui E-mail:linyq@xmu.edu.cn;shcai@xmu.edu.cn
Supported by:
Project supported by the National Natural Science Foundation of China (Grant Nos. 11275161 and 11105114).

摘要/Abstract

摘要： In many cases, high-resolution nuclear magnetic resonance (NMR) spectra are virtually impossible to obtain by conventional nuclear magnetic resonance methods because of inhomogeneity of magnetic field and inherent heterogeneity of sample. Although conventional intramolecular zero-quantum coherence (ZQC) can be used to obtain high-resolution spectrum in inhomogeneous field, the acquisition takes rather long time. In this paper, a spatially encoded intramolecular ZQC technique is proposed to fast acquire high-resolution NMR spectrum in inhomogeneous field. For the first time, the gradient-driven decoding technique is employed to selectively acquire intramolecular ZQC signals. Theoretical analyses and experimental observations demonstrate that high-resolution NMR spectral information can be retrieved within several scans even when the field inhomogeneity is severe enough to erase most spectral information. This work provides a new way to enhance the acquisition efficiency of high-resolution intramolecular ZQC spectroscopy in inhomogeneous fields.

关键词: nuclear magnetic resonance, intramolecular zero-quantum coherence, inhomogeneous magnetic fields, spatial encoding

Abstract: In many cases, high-resolution nuclear magnetic resonance (NMR) spectra are virtually impossible to obtain by conventional nuclear magnetic resonance methods because of inhomogeneity of magnetic field and inherent heterogeneity of sample. Although conventional intramolecular zero-quantum coherence (ZQC) can be used to obtain high-resolution spectrum in inhomogeneous field, the acquisition takes rather long time. In this paper, a spatially encoded intramolecular ZQC technique is proposed to fast acquire high-resolution NMR spectrum in inhomogeneous field. For the first time, the gradient-driven decoding technique is employed to selectively acquire intramolecular ZQC signals. Theoretical analyses and experimental observations demonstrate that high-resolution NMR spectral information can be retrieved within several scans even when the field inhomogeneity is severe enough to erase most spectral information. This work provides a new way to enhance the acquisition efficiency of high-resolution intramolecular ZQC spectroscopy in inhomogeneous fields.

Key words: nuclear magnetic resonance, intramolecular zero-quantum coherence, inhomogeneous magnetic fields, spatial encoding

中图分类号: (Magnetic resonance spectra)

32.30.Dx

82.56.-b (Nuclear magnetic resonance)

柯汉平, 陈浩, 林雁勤, 韦芝良, 蔡淑惠, 张志勇, 陈忠. Fast high-resolution nuclear magnetic resonance spectroscopy through indirect zero-quantum coherence detection in inhomogeneous fields[J]. 中国物理B, 2014, 23(6): 63201-063201.

Ke Han-Ping (柯汉平), Chen Hao (陈浩), Lin Yan-Qin (林雁勤), Wei Zhi-Liang (韦芝良), Cai Shu-Hui (蔡淑惠), Zhang Zhi-Yong (张志勇), Chen Zhong (陈忠). Fast high-resolution nuclear magnetic resonance spectroscopy through indirect zero-quantum coherence detection in inhomogeneous fields[J]. Chin. Phys. B, 2014, 23(6): 63201-063201.

参考文献 37

[1]	Meriles C A, Sakellariou D, Heise H, Moule A J and Pines A 2001 Science 293 82
[2]	Hurlimann M D 2007 J. Magn. Reson. 184 114
[3]	Arthanari H, Frueh D, Wagner G, Pryor B and Khaneja N 2008 J. Chem. Phys. 128 214503
[4]	Chen S, Zhang X Q, Cai S H and Chen Z 2008 Chin. Phys. B 17 915
[5]	Zheng S K, Chen Z, Chen Z W and Zhong J H 2001 Chin. Phys. 10 558
[6]	Vathyam S, Lee S and Warren W S 1996 Science 272 92
[7]	Jiang B, Liu H L, Liu M L, Ye C H and Mao X 2008 Chem. Phys. 351 33
[8]	Lin Y L, Zhang Z Y, Cai S H and Chen Z 2011 J. Am. Chem. Soc. 133 7632
[9]	de Graaf R A, Rothman D L and Behar K L 2007 J. Magn. Reson. 187 320
[10]	de Graaf R A, Klomp D W, Luijten P R and Boer V O 2013 Magn. Reson. Med. 10.1002/mrm.24701
[11]	Schanda P and Brutscher B 2005 J. Am. Chem. Soc. 127 8014
[12]	Stern A S, Li K B and Hoch J C 2002 J. Am. Chem. Soc. 124 1982
[13]	Kupce E and Freeman R 2004 J. Am. Chem. Soc. 126 6429
[14]	Kupce E and Freeman R 2005 J. Magn. Reson. 173 317
[15]	Coggins B E and Zhou P 2006 J. Magn. Reson. 182 84
[16]	Coggins B E and Zhou P 2007 J. Magn. Reson. 184 207
[17]	Coggins B E and Zhou P 2008 J. Biomol. NMR 42 225
[18]	Jiang B, Jiang X W, Xiao N, Zhang X, Jiang L, Mao X A and Liu M L 2010 J. Magn. Reson. 204 165
[19]	Mandelshtam V A, Taylor H S and Shaka A J 1998 J. Magn. Reson. 133 304
[20]	Kupce E and Freeman R 2003 J. Magn. Reson. 162 300
[21]	Kupce E and Freeman R 2003 J. Magn. Reson. 162 158
[22]	Kupce E and Freeman R 2003 J. Magn. Reson. 163 56
[23]	Frydman L, Lupulescu A and Scherf T 2003 J. Am. Chem. Soc. 125 9204
[24]	Frydman L, Scherf T and Lupulescu A 2002 Proc. Nat. Acad. Sci. USA 99 15858
[25]	Tal A, Shapira B and Frydman L 2005 J. Magn. Reson. 176 107
[26]	Wu C, Zhao M F, Cai S H, Lin Y L and Chen Z 2010 J. Magn. Reson. 204 82
[27]	Panek R, Granwehr J, Leggett J and Kockenberger W 2010 Phys. Chem. Chem. Phys. 12 5771
[28]	Pelupessy P 2003 J. Am. Chem. Soc. 125 12345
[29]	Herrera A, Fernandez-Valle E, Martinez-Alvarez R, Molero D, Pardo Z D, Saez E and Gal M 2009 Angew. Chem. Int. Ed. 48 6274
[30]	Zhang Z Y, Chen H, Wu C, Wu R, Cai S H and Chen Z 2013 J. Magn. Reson. 227 39
[31]	Giraudeau P and Akoka S 2007 J. Magn. Reson. 186 352
[32]	Roussel T, Giraudeau P, Rainey H, Akoka S and Cavassila S 2012 J. Magn. Reson. 215 50
[33]	Shrot Y and Frydman L 2008 J. Magn. Reson. 195 226
[34]	Gal M, Schanda P, Brutscher B and Frydman L 2007 J. Am. Chem. Soc. 129 1372
[35]	Giraudeau P, Shrot Y and Frydman L 2009 J. Am. Chem. Soc. 131 13902
[36]	Tal A and Frydman L 2010 Prog. Nucl. Magn. Reson. Spectrosc. 57 241
[37]	Pelupessy P, Duma L and Bodenhausen G 2008 J. Magn. Reson. 194 169

Fast high-resolution nuclear magnetic resonance spectroscopy through indirect zero-quantum coherence detection in inhomogeneous fields

Fast high-resolution nuclear magnetic resonance spectroscopy through indirect zero-quantum coherence detection in inhomogeneous fields

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