Solid solubility and photoluminescence of Y3Al5O12：Ce3+ prepared by using (Y1-xCex)2O3 as precursor

doi:10.1088/1674-1056/23/4/048106

中国物理B ›› 2014, Vol. 23 ›› Issue (4): 48106-048106.doi: 10.1088/1674-1056/23/4/048106

• INTERDISCIPLINARY PHYSICS AND RELATED AREAS OF SCIENCE AND TECHNOLOGY • 上一篇下一篇

Solid solubility and photoluminescence of Y₃Al₅O₁₂：Ce³⁺ prepared by using (Y_1-xCe_x)₂O₃ as precursor

刘思佳^a, 彭同江^a, 宋振^b, 边柳^b, 宋功保^a, 刘泉林^b

a School of Materials Science & Engineering, Southwest University of Science and Technology, Mianyang 621010, China;
b School of Materials Science & Engineering and State Key Laboratory for Advanced Metals and Materials, University of Science and Technology Beijing, Beijing 100083, China

收稿日期:2013-09-27 修回日期:2013-12-16 出版日期:2014-04-15 发布日期:2014-04-15
基金资助:
Project supported by the National Natural Science Foundation of China (Grant No. 51272027) and the Ph. D. Program Foundation of Education Ministry of China (Grant No. 20100006110011).

Solid solubility and photoluminescence of Y₃Al₅O₁₂：Ce³⁺ prepared by using (Y_1-xCe_x)₂O₃ as precursor

Liu Si-Jia (刘思佳)^a, Peng Tong-Jiang (彭同江)^a, Song Zhen (宋振)^b, Bian Liu (边柳)^b, Song Gong-Bao (宋功保)^a, Liu Quan-Lin (刘泉林)^b

a School of Materials Science & Engineering, Southwest University of Science and Technology, Mianyang 621010, China;
b School of Materials Science & Engineering and State Key Laboratory for Advanced Metals and Materials, University of Science and Technology Beijing, Beijing 100083, China

Received:2013-09-27 Revised:2013-12-16 Online:2014-04-15 Published:2014-04-15
Contact: Liu Quan-Lin E-mail:qlliu@ustb.edu.cn
About author:81.20.-n; 78.55.Hx; 61.55.Fn
Supported by:
Project supported by the National Natural Science Foundation of China (Grant No. 51272027) and the Ph. D. Program Foundation of Education Ministry of China (Grant No. 20100006110011).

摘要/Abstract

摘要： Trivalent cerium-doped yttrium aluminum garnet (YAG:Ce³⁺) phosphors are synthesized by solid-state reaction method through using (Y_1-xCe_x)₂O₃ solid solutions as precursors. Solid solubility limits of Ce³⁺ replacing Y³⁺ in Y₂O₃ and YAG are determined to be 40% and 7.5%, respectively, based on the relationship between the lattice parameter and chemical composition. Using (Y_1-xCe_x)₂O₃ as precursors we synthesize YAG:Ce³⁺single phase at 1450℃ and N₂ atmosphere. However, under the same conditions using CeO₂ there exists a second phase YAlO₃ as impurity. The photoluminescence intensity of YAG:Ce³⁺ increases monotonically with the increase of Ce concentration until it reaches a maximum at solid solubility limits of Ce³⁺ in YAG.

关键词: luminescence, YAG, solid solubility, LED

Abstract: Trivalent cerium-doped yttrium aluminum garnet (YAG:Ce³⁺) phosphors are synthesized by solid-state reaction method through using (Y_1-xCe_x)₂O₃ solid solutions as precursors. Solid solubility limits of Ce³⁺ replacing Y³⁺ in Y₂O₃ and YAG are determined to be 40% and 7.5%, respectively, based on the relationship between the lattice parameter and chemical composition. Using (Y_1-xCe_x)₂O₃ as precursors we synthesize YAG:Ce³⁺single phase at 1450℃ and N₂ atmosphere. However, under the same conditions using CeO₂ there exists a second phase YAlO₃ as impurity. The photoluminescence intensity of YAG:Ce³⁺ increases monotonically with the increase of Ce concentration until it reaches a maximum at solid solubility limits of Ce³⁺ in YAG.

Key words: luminescence, YAG, solid solubility, LED

中图分类号: (Methods of materials synthesis and materials processing)

81.20.-n

78.55.Hx (Other solid inorganic materials)

刘思佳, 彭同江, 宋振, 边柳, 宋功保, 刘泉林. Solid solubility and photoluminescence of Y₃Al₅O₁₂：Ce³⁺ prepared by using (Y_1-xCe_x)₂O₃ as precursor[J]. 中国物理B, 2014, 23(4): 48106-048106.

Liu Si-Jia (刘思佳), Peng Tong-Jiang (彭同江), Song Zhen (宋振), Bian Liu (边柳), Song Gong-Bao (宋功保), Liu Quan-Lin (刘泉林). Solid solubility and photoluminescence of Y₃Al₅O₁₂：Ce³⁺ prepared by using (Y_1-xCe_x)₂O₃ as precursor[J]. Chin. Phys. B, 2014, 23(4): 48106-048106.

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Solid solubility and photoluminescence of Y₃Al₅O₁₂：Ce³⁺ prepared by using (Y_1-xCe_x)₂O₃ as precursor

Solid solubility and photoluminescence of Y₃Al₅O₁₂：Ce³⁺ prepared by using (Y_1-xCe_x)₂O₃ as precursor

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