Photoluminescence characteristics and energy transfer between Bi3+ and Eu3+ in Na2O–CaO–GeO2–SiO2 glass

doi:10.1088/1674-1056/23/12/127803

›› 2014, Vol. 23 ›› Issue (12): 127803-127803.doi: 10.1088/1674-1056/23/12/127803

• CONDENSED MATTER: ELECTRONIC STRUCTURE, ELECTRICAL, MAGNETIC, AND OPTICAL PROPERTIES • 上一篇下一篇

Photoluminescence characteristics and energy transfer between Bi³⁺ and Eu³⁺ in Na₂O–CaO–GeO₂–SiO₂ glass

黎千跃, 徐旭辉, 张步豪, 吴玉梅, 邱建备, 余雪

College of Materials Science and Engineering, Kunming University of Science and Technology, Kunming 650093, China

收稿日期:2014-05-15 修回日期:2014-07-10 出版日期:2014-12-15 发布日期:2014-12-15
基金资助:
Project supported by the National Natural Science Foundation of China (Grant Nos. 11204113 and 61308091) and the Specialized Research Fund for the Doctoral Program of Higher Education of China (Grant No. 20115314120001).

Photoluminescence characteristics and energy transfer between Bi³⁺ and Eu³⁺ in Na₂O–CaO–GeO₂–SiO₂ glass

Li Qian-Yue (黎千跃), Xu Xu-Hui (徐旭辉), Zhang Bu-Hao (张步豪), Wu Yu-Mei (吴玉梅), Qiu Jian-Bei (邱建备), Yu Xue (余雪)

College of Materials Science and Engineering, Kunming University of Science and Technology, Kunming 650093, China

Received:2014-05-15 Revised:2014-07-10 Online:2014-12-15 Published:2014-12-15
Contact: Yu Xue E-mail:yuyu6593@126.com
Supported by:
Project supported by the National Natural Science Foundation of China (Grant Nos. 11204113 and 61308091) and the Specialized Research Fund for the Doctoral Program of Higher Education of China (Grant No. 20115314120001).

摘要/Abstract

摘要： We report the photoluminescence (PL) of Eu³⁺-doped glass with Bi³⁺ as a sensitizer. The specific glass system with the strong enhancement of the red emission of Eu³⁺ is obtained by adding a small number of Bi³⁺ ions instead of increasing the Eu³⁺ concentration. The emission band of Bi³⁺ overlaps with the excitation band of Eu³⁺ and the lifetime decay curves, resulting in a very efficient energy transfer from Bi³⁺ to Eu³⁺. The probability of energy transfer is strongly dependent on Bi³⁺ concentration. In addition, the intensity of 4f–4f transition is much stronger than that of a charge-transfer (CT) band in the excitation spectrum, which indicates that the Na₂O–CaO–GeO₂-SiO₂ glass is a suitable red-emitting phosphor with high stability as a candidate for light-emitting diodes (LEDs).

关键词: germinate glass, energy transfer, thermal quenching

Abstract: We report the photoluminescence (PL) of Eu³⁺-doped glass with Bi³⁺ as a sensitizer. The specific glass system with the strong enhancement of the red emission of Eu³⁺ is obtained by adding a small number of Bi³⁺ ions instead of increasing the Eu³⁺ concentration. The emission band of Bi³⁺ overlaps with the excitation band of Eu³⁺ and the lifetime decay curves, resulting in a very efficient energy transfer from Bi³⁺ to Eu³⁺. The probability of energy transfer is strongly dependent on Bi³⁺ concentration. In addition, the intensity of 4f–4f transition is much stronger than that of a charge-transfer (CT) band in the excitation spectrum, which indicates that the Na₂O–CaO–GeO₂-SiO₂ glass is a suitable red-emitting phosphor with high stability as a candidate for light-emitting diodes (LEDs).

Key words: germinate glass, energy transfer, thermal quenching

中图分类号: (Photoluminescence, properties and materials)

78.55.-m

黎千跃, 徐旭辉, 张步豪, 吴玉梅, 邱建备, 余雪. Photoluminescence characteristics and energy transfer between Bi³⁺ and Eu³⁺ in Na₂O–CaO–GeO₂–SiO₂ glass[J]. , 2014, 23(12): 127803-127803.

Li Qian-Yue (黎千跃), Xu Xu-Hui (徐旭辉), Zhang Bu-Hao (张步豪), Wu Yu-Mei (吴玉梅), Qiu Jian-Bei (邱建备), Yu Xue (余雪). Photoluminescence characteristics and energy transfer between Bi³⁺ and Eu³⁺ in Na₂O–CaO–GeO₂–SiO₂ glass[J]. Chin. Phys. B, 2014, 23(12): 127803-127803.

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Photoluminescence characteristics and energy transfer between Bi³⁺ and Eu³⁺ in Na₂O–CaO–GeO₂–SiO₂ glass

Photoluminescence characteristics and energy transfer between Bi³⁺ and Eu³⁺ in Na₂O–CaO–GeO₂–SiO₂ glass

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